General Quadridavyne Information
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Chemical Formula: |
(Na,K)6Ca2Al6Si6O24Cl4 |
Composition: |
Molecular Weight = 1,103.19 gm |
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Potassium 4.96 % K 5.98 % K2O |
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Sodium 8.34 % Na 11.24 % Na2O |
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Calcium 7.99 % Ca 11.18 % CaO |
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Aluminum 14.67 % Al 27.73 % Al2O3 |
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Silicon 15.28 % Si 32.68 % SiO2 |
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Sulfur 0.58 % S 1.45 % SO3 |
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Chlorine 12.21 % Cl 12.21 % Cl |
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- % Cl -2.76 % -O=Cl2 |
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Oxygen 35.97 % O |
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______ ______ |
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100.00 % 99.71 % = TOTAL OXIDE |
Empirical Formula: |
Na4K1.4Ca2.2Al6Si6O24Cl3.8(SO4)0.2 |
Environment: |
In volcanic ash from the 1906 eruption of Vesuvius. |
IMA Status: |
Approved IMA 1994 |
Locality: |
From Ottaviano, near Naples, Campania, Italy. Link to MinDat.org Location Data. |
Name Origin: |
From the Latin "quad" for four, as the mineral has four times the unit cell volume of the related mineral species davyne. |
Synonym: |
ICSD 64812 |
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IMA1990-054 |
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PDF 46-1474 |
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Quadridavyne Image |
Images:
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Quadridavyne
Comments: Colorless hexagonal crystals of quadridavyne.
Location: Ettringer Bellerberg, Ettringen, near Mayen, Eifel Mts, Rhineland-Palatinate, Germany.
Scale: Picture size 3 mm.
© Thomas Witzke / Abraxas-Verlag |
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Quadridavyne Crystallography
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Axial Ratios: |
a:c = 1:0.20841 |
Cell Dimensions: |
a = 25.771, c = 5.371, Z = 4; V = 3,089.22 Den(Calc)= 2.37 |
Crystal System: |
Hexagonal - DipyramidalH-M Symbol (6/m) Space Group: P 63/m |
X Ray Diffraction: |
By Intensity(I/Io): 3.31(1), 3.71(1), 4.85(0.7), |
Crystal Structure:
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Bonaccorsi E , Merlino S , Orlandi P , Pasero M , Vezzalini G , European Journal of Mineralogy , 6 (1994) p.481-487, Quadridavyne, [(Na,K)6Cl2][Ca2Cl2][Si6Al6O24], a new feldspathoid, mineral from Vesuvius area, Note: Cl1 y-coordinate altered, Locality: Vesuvius, Italy
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Physical Properties of Quadridavyne
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Cleavage: |
[0001] Perfect, [1120] Distinct |
Color: |
Colorless. |
Density: |
2.335 |
Diaphaniety: |
Transparent |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Habit: |
Hexagonal - Six-sided crystal shape in cross-section or habit. |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Hardness: |
5 - Apatite |
Luster: |
Vitreous (Glassy) |
Streak: |
white |
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Optical Properties of Quadridavyne
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Gladstone-Dale: |
CI meas= -0.018 (Superior) - where the CI = (1-KPDmeas/KC) CI calc= -0.003 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2238,KPDmeas= 0.2272,KC= 0.2231 |
Optical Data: |
Uniaxial (+), w=1.529, e=1.532, bire=0.0030. |
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Calculated Properties of Quadridavyne
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Electron Density: |
relectron=2.33 gm/cc note: rQuadridavyne =2.37 gm/cc. |
Fermion Index |
Fermion Index = 0.00746 Boson Index = 0.99254 |
Photoelectric: |
PEQuadridavyne = 3.46 barns/electron U=PEQuadridavyne x relectron= 8.08 barns/cc. |
Radioactivity: |
GRapi = 70.43 (Gamma Ray American Petroleum Institute Units)
Estimated Radioactivity from Quadridavyne - barely detectable
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Quadridavyne Classification
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Dana Class: |
76.2.5.12 (76)Tectosilicate Al-Si Framework |
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(76.2)Feldspathoids and related species |
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(76.2.5)Cancrinite group |
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76.2.5.1 Afghanite (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3·(H2O) P 63/mmc, P 63mc, or P 62c Hex |
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76.2.5.2 Bystrite (Na,K)7Ca(Si6Al6)O24S4.5·(H2O) P 31c 3m |
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76.2.5.3 Cancrinite Na6Ca2Al6Si6O24(CO3)2 P 63 6 |
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76.2.5.4 Cancrisilite Na7Al5Si7O24(C03)·3(H2O) P 63 6 |
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76.2.5.5 Davyne Na4K2Ca2Si6Al6O24(SO4)Cl2 P 63/m 6/m |
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76.2.5.6 Franzinite [(Na,K)30Ca10][Si30Al30O120](SO4)10·2(H2O) P 321 3 2 |
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76.2.5.7 Giuseppettite [Na42K16Ca6]S64Si48Al48O192(SO4)10Cl2·5H2O P 31c 3m |
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76.2.5.8 Hydroxycancrinite Na4(AlSiO4)3(OH)·(H2O) P 63 6 |
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76.2.5.9 Liottite (Ca,Na,K)8(Si,Al)12O24[(SO4),(CO3),Cl,OH]4·(H2O) P 6m2 6 m2 |
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76.2.5.10 Microsommite (Na,Ca,K)7-8(Si,Al)12O24(Cl,SO4)2-3 P 6322 6 2 2 |
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76.2.5.11 Pitiglianoite Na6K2Si6Al6O24(SO4)·2(H2O) P 63 6 |
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76.2.5.12 Quadridavyne (Na,K)6Ca2Al6Si6O24Cl4 P 63/m 6/m |
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76.2.5.13 Sacrofanite (Na,Ca,K)9Si6Al6O24[(OH),(SO4),(CO3),Cl)]4·n(H2O) P 63/mmc ? 6/m 2/m 2/m |
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76.2.5.14 Tounkite (Na,Ca,K)8Al6Si6O24(SO4)2Cl·(H2O) P 6222 6 2 2 |
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76.2.5.15 Vishnevite (Na,Ca,K)6(Si,Al)12O24[(SO4),(CO3),Cl2]2-4·n(H2O) P 6322 6 2 2 |
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76.2.5.16 Wenkite Ba4Ca6(Si,Al)20O39(OH)2(SO4)3·n(H2O)(?) P 62m 6 m2 |
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76.2.5.17 Marinellite! [(Na,K)42Ca6](Si36Al36O144)(SO4)8Cl2·6(H2O) P 31c or P 2c Trig |
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76.2.5.18 IMA2004-043! (Na37K9Ca10)S56(Si42Al42)S84O168(SO4)12·6(H2O) P 63/m 6/m 2/m 2/m |
Strunz Class: |
VIII/J.09-25 VIII - Silicates |
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VIII/J - Tectosilicates (network) with anions unfamiliar to the tetraheders |
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VIII/J.09 - Cancrinite group |
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VIII/J.09-05 Hydroxycancrinite Na4(AlSiO4)3(OH)·(H2O) P 63 6 |
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VIII/J.09-10 Cancrinite Na6Ca2Al6Si6O24(CO3)2 P 63 6 |
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VIII/J.09-15 Cancrisilite Na7Al5Si7O24(C03)·3(H2O) P 63 6 |
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VIII/J.09-20 Davyne Na4K2Ca2Si6Al6O24(SO4)Cl2 P 63/m 6/m |
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VIII/J.09-25 Quadridavyne (Na,K)6Ca2Al6Si6O24Cl4 P 63/m 6/m |
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VIII/J.09-30 Microsommite (Na,Ca,K)7-8(Si,Al)12O24(Cl,SO4)2-3 P 6322 6 2 2 |
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VIII/J.09-40 Giuseppettite [Na42K16Ca6]S64Si48Al48O192(SO4)10Cl2·5H2O P 31c 3m |
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VIII/J.09-45 Bystrite (Na,K)7Ca(Si6Al6)O24S4.5·(H2O) P 31c 3m |
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VIII/J.09-50 Afghanite (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3·(H2O) P 63/mmc, P 63mc, or P 62c Hex |
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VIII/J.09-55 Tounkite (Na,Ca,K)8Al6Si6O24(SO4)2Cl·(H2O) P 6222 6 2 2 |
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VIII/J.09-60 Sacrofanite (Na,Ca,K)9Si6Al6O24[(OH),(SO4),(CO3),Cl)]4·n(H2O) P 63/mmc ? 6/m 2/m 2/m |
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VIII/J.09-65 Pitiglianoite Na6K2Si6Al6O24(SO4)·2(H2O) P 63 6 |
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VIII/J.09-70 Vishnevite (Na,Ca,K)6(Si,Al)12O24[(SO4),(CO3),Cl2]2-4·n(H2O) P 6322 6 2 2 |
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VIII/J.09-80 Franzinite [(Na,K)30Ca10][Si30Al30O120](SO4)10·2(H2O) P 321 3 2 |
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VIII/J.09-90 Liottite (Ca,Na,K)8(Si,Al)12O24[(SO4),(CO3),Cl,OH]4·(H2O) P 6m2 6 m2 |
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VIII/J.09-100 Wenkite Ba4Ca6(Si,Al)20O39(OH)2(SO4)3·n(H2O)(?) P 62m 6 m2 |
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Other Quadridavyne Information
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References: |
NAME( AntBidBlaNic2) PHYS. PROP.(Am.Min.,Vol.80,p631,1995) OPTIC PROP.(Am.Min.,Vol.80,p631,1995) |
See Also: |
Links to other databases for Quadridavyne :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (MinSocAm)
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 - WWW-MINCRYST
14 -École des Mines de Paris
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Quadridavyne
(Na,K)6Ca2Al6Si6O24Cl4
Dana No: 76.2.5.12 Strunz No: VIII/J.09-25
Locality:
Notes:
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