Davyne Mineral Data

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General Davyne Information

Chemical Formula:

Na4K2Ca2Si6Al6O24(SO4)Cl2

Composition:

Molecular Weight = 1,084.25 gm

Potassium 5.63 % K 6.78 % K₂O

Sodium 7.51 % Na 10.12 % Na₂O

Calcium 8.98 % Ca 12.57 % CaO

Aluminum 15.43 % Al 29.15 % Al₂O₃

Silicon 15.02 % Si 32.14 % SiO₂

Sulfur 1.77 % S 4.43 % SO₃

Chlorine 6.70 % Cl 6.70 % Cl

- % Cl -1.51 % -O=Cl₂

Oxygen 38.96 % O

______ ______

100.00 % 100.38 % = TOTAL OXIDE

Empirical Formula:

Na_3.54Ca_2.43K_1.56Al_6.2Si_5.8O₂₄Cl_2.05(SO₄)_0.6

Environment:

In volcanic ejecta and in leucite-rich lavas.

IMA Status:

Valid Species (Pre-IMA) 1825

Locality:

Mte. Somma, Vesuvius, Italy. Link to MinDat.org Location Data.

Name Origin:

Named for Sir Humphrey Davy (1778-1829), famous English chemist who discovered the following elements: B, Ba, Ca, K, Mg, Na, and Sr.

Name Pronunciation:

Davyne

Synonym:

ICSD 68940

PDF 20-379

Davyne Image

Images:

Davyne

Comments: Yellow translucent micro crystal of davyne in sanidine.
Location: Laacher See, Rheinland-Pfalz, Germany. Scale: See Photo.
© Jeff Weissman / Photographic Guide to Mineral Species

Davyne Crystallography

Axial Ratios:

a:c = 1:0.42251

Cell Dimensions:

a = 12.705, c = 5.368, Z = 1; V = 750.40 Den(Calc)= 2.40

Crystal System:

Hexagonal - DipyramidalH-M Symbol (6/m) Space Group: P 6₃/m

$Help on X Ray Diffraction:$ X Ray Diffraction:

By Intensity(I/I_o): 3.28(1), 3.67(1), 4.8(1),

Crystal Structure:

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Hassan I , Grundy H D , The Canadian Mineralogist , 28 (1990) p.341-349, Structure of davyne and implications for stacking faults, Sample BM1907,210

View Additional jPOWD Structure files for Davyne
[1] [2]

Physical Properties of Davyne

Cleavage:

{1010} Perfect, {0001} Indistinct

Color:

Colorless, White.

Density:

2.42 - 2.53, Average = 2.47

Diaphaneity:

Transparent

Fracture:

Brittle - Conchoidal - Very brittle fracture producing small, conchoidal fragments.

Habit:

Hexagonal - Six-sided crystal shape in cross-section or habit.

Habit:

Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline).

Hardness:

6 - Orthoclase

Luster:

Vitreous (Glassy)

Streak:

white

Optical Properties of Davyne

Gladstone-Dale:

CI meas= 0.021 (Excellent) - where the CI = (1-KPDmeas/KC)
CI calc= -0.009 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2171,KPDmeas= 0.2105,KC= 0.2151
Ncalc = 1.52 - 1.54

Optical Data:

Uniaxial (+), w=1.518-1.522, e=1.517-1.527, bire=0.0010-0.0050.

Calculated Properties of Davyne

Electron Density:

Bulk Density (Electron Density)=2.37 gm/cc
note: Specific Gravity of Davyne =2.40 gm/cc.

Fermion Index:

Fermion Index = 0.0074642155
Boson Index = 0.9925357845

Photoelectric:

PE_Davyne= 3.36 barns/electron
U=PE_Davyne x r_electron= 7.95 barns/cc.

Radioactivity:

GRapi = 80.02 (Gamma Ray American Petroleum Institute Units)
Concentration of Davyne per GRapi unit = 1.25 (%)

Estimated Radioactivity from Davyne - barely detectable

Davyne Classification

Dana Class:

76.02.05.05 (76)Tectosilicate Al-Si Framework

(76.02)Feldspathoids and related species

(76.02.05)Cancrinite group

76.02.05.01 Afghanite (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3•(H2O) P 6₃/mmc, P 6₃mc, or P 62c Hex

76.02.05.02 Bystrite (Na,K)7Ca(Si6Al6)O24S4.5•(H2O) P 3₁c 3m

76.02.05.03 Cancrinite Na6Ca2Al6Si6O24(CO3)2 P 6₃ 6

76.02.05.04 Cancrisilite Na7Al5Si7O24(C03)•3(H2O) P 6₃ 6

76.02.05.05 Davyne Na4K2Ca2Si6Al6O24(SO4)Cl2 P 6₃/m 6/m

76.02.05.06 Franzinite [(Na,K)30Ca10][Si30Al30O120](SO4)10•2(H2O) P 3₂1 3 2

76.02.05.07 Giuseppettite [Na42K16Ca6]S64Si48Al48O192(SO4)10Cl2•5H2O P 3₁c 3m

76.02.05.08 Hydroxycancrinite Na4(AlSiO4)3(OH)•(H2O) P 6₃ 6

76.02.05.09 Liottite (Ca,Na,K)8(Si,Al)12O24[(SO4),(CO3),Cl,OH]4•(H2O) P 6m2 6 m2

76.02.05.10 Microsommite (Na,Ca,K)7-8(Si,Al)12O24(Cl,SO4)2-3 P 6₃22 6 2 2

76.02.05.11 Pitiglianoite Na6K2Si6Al6O24(SO4)•2(H2O) P 6₃ 6

76.02.05.12 Quadridavyne (Na,K)6Ca2Al6Si6O24Cl4 P 6₃/m 6/m

76.02.05.13 Sacrofanite (Na,Ca,K)9Si6Al6O24[(OH),(SO4),(CO3),Cl)]4•n(H2O) P 6₃/mmc ? 6/m 2/m 2/m

76.02.05.14 Tounkite (Na,Ca,K)8Al6Si6O24(SO4)2Cl•(H2O) P 6₂22 6 2 2

76.02.05.15 Vishnevite (Na,Ca,K)6(Si,Al)12O24[(SO4),(CO3),Cl2]2-4•n(H2O) P 6₃22 6 2 2

76.02.05.16 Wenkite Ba4Ca6(Si,Al)20O39(OH)2(SO4)3•n(H2O)(?) P 62m 6 m2

76.02.05.17 Marinellite! [(Na,K)42Ca6](Si36Al36O144)(SO4)8Cl2•6(H2O) P 3₁c or P 2c Trig

76.02.05.18 Farneseite! (Na37K9Ca10)S56(Si42Al42)S84O168(SO4)12•6(H2O) P 6₃/m 6/m 2/m 2/m

76.02.05.19 Alloriite! Na5K1.5Ca(Si6Al6O24)(SO4)(OH)0.5•H2O P 3₁c 3m

76.02.05.20 Biachellaite (Na,Ca,K)8(Si6Al6O24)(SO4)2(OH)0.5•H2O P 3 3

76.02.05.21 IMA2008-006! [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33•4H2O P 3 3

76.02.05.22 Kyanoxalite! Na7(Al5-6Si6-7O24)(C2O4)0.5-1.0•5H2O P 6₃ 6

76.02.05.23 IMA2008-065! (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) P 6₃ 6

Strunz Class:

09.FB.05 09 - SILICATES (Germanates)

09.F - Tektosilicates without Zeolitic H2O

09.FB -Tektosilicates with additional anions

09.FB.05 Bystrite (Na,K)7Ca(Si6Al6)O24S4.5•(H2O) P 3₁c 3m

09.FB.05 Afghanite (Na,Ca,K)8(Si,Al)12O24(SO4,Cl,CO3)3•(H2O) P 6₃/mmc, P 6₃mc, or P 62c Hex

09.FB.05 Cancrisilite Na7Al5Si7O24(C03)•3(H2O) P 6₃ 6

09.FB.05 Cancrinite Na6Ca2Al6Si6O24(CO3)2 P 6₃ 6

09.FB.05 Hydroxycancrinite Na4(AlSiO4)3(OH)•(H2O) P 6₃ 6

09.FB.05 Franzinite [(Na,K)30Ca10][Si30Al30O120](SO4)10•2(H2O) P 3₂1 3 2

09.FB.05 Liottite (Ca,Na,K)8(Si,Al)12O24[(SO4),(CO3),Cl,OH]4•(H2O) P 6m2 6 m2

09.FB.05 Davyne Na4K2Ca2Si6Al6O24(SO4)Cl2 P 6₃/m 6/m

09.FB.05 Giuseppettite [Na42K16Ca6]S64Si48Al48O192(SO4)10Cl2•5H2O P 3₁c 3m

09.FB.05 Quadridavyne (Na,K)6Ca2Al6Si6O24Cl4 P 6₃/m 6/m

09.FB.05 Pitiglianoite Na6K2Si6Al6O24(SO4)•2(H2O) P 6₃ 6

09.FB.05 Microsommite (Na,Ca,K)7-8(Si,Al)12O24(Cl,SO4)2-3 P 6₃22 6 2 2

09.FB.05 Vishnevite (Na,Ca,K)6(Si,Al)12O24[(SO4),(CO3),Cl2]2-4•n(H2O) P 6₃22 6 2 2

09.FB.05 Sacrofanite (Na,Ca,K)9Si6Al6O24[(OH),(SO4),(CO3),Cl)]4•n(H2O) P 6₃/mmc ? 6/m 2/m 2/m

09.FB.05 Marinellite! [(Na,K)42Ca6](Si36Al36O144)(SO4)8Cl2•6(H2O) P 3₁c or P 2c Trig

09.FB.05 Tounkite (Na,Ca,K)8Al6Si6O24(SO4)2Cl•(H2O) P 6₂22 6 2 2

09.FB.05 IMA2008-065! (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) P 6₃ 6

09.FB.05 Farneseite! (Na37K9Ca10)S56(Si42Al42)S84O168(SO4)12•6(H2O) P 6₃/m 6/m 2/m 2/m

09.FB.05 Biachellaite (Na,Ca,K)8(Si6Al6O24)(SO4)2(OH)0.5•H2O P 3 3

09.FB.05 IMA2008-006! [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33•4H2O P 3 3

09.FB.05 Alloriite! Na5K1.5Ca(Si6Al6O24)(SO4)(OH)0.5•H2O P 3₁c 3m

Other Davyne Information

References:

NAME( AntBidBlaNic2) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Ford32)

See Also:

Links to other databases for Davyne :
1 - Am. Min. Crystal Structure Database
2 - Athena
3 - EUROmin Project
4 - Ecole des Mines de Paris
5 - GeoScienceWorld
6 - Google Images
7 - Google Scholar
8 - Handbook of Mineralogy (MinSocAm)
9 - Handbook of Mineralogy (UofA)
10 - MinDAT
11 - Mineralienatlas (Deutsch)
12 - Online Mineral Museum
13 - QUT Mineral Atlas
14 - Ruff.Info
15 - WWW-MINCRYST

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Davyne

Na4K2Ca2Si6Al6O24(SO4)Cl2
Dana No: 76.02.05.05 Strunz No: 09.FB.05
Locality:

Notes: