General Monazite-(Sm) Information
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Chemical Formula: |
SmPO4 |
Composition: |
Molecular Weight = 221.25 gm |
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Calcium 1.81 % Ca 2.53 % CaO |
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Cerium 9.50 % Ce 11.13 % Ce2O3 |
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Samarium 13.59 % Sm 15.76 % Sm2O3 |
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Gadolinium 14.21 % Gd 16.38 % Gd2O3 |
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Thorium 15.73 % Th 17.90 % ThO2 |
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Phosphorus 12.60 % P 28.87 % P2O5 |
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Neodymium 6.52 % Nd 7.60 % Nd2O3 |
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Oxygen 26.03 % O |
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______ ______ |
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100.00 % 100.18 % = TOTAL OXIDE |
Empirical Formula: |
Sm0.2Gd0.2Th0.15Ce0.15Ca0.1Nd0.1(PO4)0.9 |
Environment: |
Lepidolite-subtype granitic pegmatite within the Greer Lake intrusion of pegmatitic leucogranite. Monazite group, structure |
IMA Status: |
Approved IMA 2002 (Dana # Added) |
Locality: |
Anne Claim #3, 1.2 km northwest of Greer Lake, southeatern Mintoba, Canada. Link to MinDat.org Location Data. |
Name Origin: |
Named as the Sm-dominant member of the monazite series. |
Synonym: |
ICSD 79751 |
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IMA2001-001 |
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PDF 46-1329 |
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Monazite-(Sm) Image |
Images:
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Monazite-(Sm)
Comments: Back-scattered electron image of the main aggregate of monazite-(Sm) and manganocolumbite (C) embedded in quartz (black). Variations in brightness of the monazite-(Sm) are controlled by the Th content, whereas the ratio Nb/Ta affects manganotantalite.
Location: Annie Claim #3 pod, Greer Lake intrusion, Archean Bird River Subprovince of the Superior Province, Southeastern Manitoba, Canada.
Scale: Grain size 0.8 mm.
© Canadian Mineralogist |
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Monazite-(Sm) Crystallography
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Axial Ratios: |
a:b:c =0.9695:1:0.9296 |
Cell Dimensions: |
a = 6.725, b = 6.936, c = 6.448, Z = 4; beta = 104.02° V = 291.80 Den(Calc)= 5.04 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/n |
X Ray Diffraction: |
By Intensity(I/Io): 3.065(1)(120), 2.857(0.9)(112,012), 4.162(0.8)(111),3.264(0.7)(200), 4.647(0.5)(011), 3.492(0.4)(111,020), 5.19(0.4), |
Crystal Structure:
Mouse
drag1 - LMB Manipulate Structure
drag2 - RMB Resize/Rotate
Keyboard
S - Stereo Pair on/off
H - Help Screen
I - Data Info
A - Atoms On/Off
P - Polyhedra On/Off
B - Bonds On/Off
Help on Above
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Ni Y , Hughes J M , Mariano A N , American Mineralogist , 80 (1995) p.21-26, Crystal chemistry of the monazite and xenotime structures, Sm(PO4)
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Physical Properties of Monazite-(Sm)
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Cleavage: |
[???] Good |
Color: |
Yellowish. |
Diaphaniety: |
Translucent to transparent |
Fracture: |
Brittle - Uneven - Very brittle fracture producing uneven fragments. |
Habit: |
Platy - Sheet forms (e.g. micas). |
Habit: |
Subhedral Crystals - Occurs as crystals which tend to exhibit a recognizable crystal shape. |
Luster: |
Vitreous - Greasy |
Streak: |
white |
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Optical Properties of Monazite-(Sm)
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Gladstone-Dale: |
CI calc= -0.005 (Superior) - where the CI = (1-KPDcalc/KC) KPDcalc= 0.1559,KC= 0.1551 |
Optical Data: |
Biaxial (+), a=1.768, b=1.771, g=1.818, bire=0.0500 |
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Calculated Properties of Monazite-(Sm)
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Electron Density: |
relectron=4.45 gm/cc note: rMonazite-(Sm) =5.04 gm/cc. |
Fermion Index |
Fermion Index = 0.15122 Boson Index = 0.84878 |
Photoelectric: |
PEMonazite-(Sm) = 658.05 barns/electron U=PEMonazite-(Sm) x relectron=2,929.08 barns/cc. |
Radioactivity: |
GRapi = 297,115.57 (Gamma Ray American Petroleum Institute Units)
Monazite-(Sm) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
102.37 ± 25.59 grams of pure Monazite-(Sm) .
Estimated Radioactivity from Monazite-(Sm) - strong
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.24 cm |
7,064,893 |
1.91E-04 |
297,115.57 |
97.68 |
| 100 gm / 3.36 cm |
706,489 |
1.91E-05 |
29,711.56 |
9.77 |
| 10 gm / 1.56 cm |
70,649 |
1.91E-06 |
2,971.16 |
0.98 |
| 1 gm / 7.24 mm |
7,065 |
1.91E-07 |
297.12 |
0.10 |
| 0.1 gm / 3.36 mm |
706 |
1.91E-08 |
29.71 |
0.01 |
| 0.01 gm / 1.56 mm |
71 |
1.91E-09 |
2.97 |
0.00 |
| 0.001 gm / 0.72 mm |
7 |
1.91E-10 |
0.30 |
0.00 |
Weight of pure Monazite-(Sm) in grams (gm) and Calculated Diameter of a Sphere with a Density of 5.04 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
**
Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
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Monazite-(Sm) Classification
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Dana Class: |
38.4.3.7 (38)Anhydrous Phosphates, etc |
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(38.4)A+ XO4 |
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(38.4.3)Monazite Group (Monoclinic: P21/n) |
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38.4.3.1 Monazite-(Ce) (Ce,La,Nd,Th)PO4 P 21/n 2/m |
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38.4.3.2 Monazite-(La) (La,Ce,Nd)PO4 P 21/n 2/m |
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38.4.3.3 Cheralite-(Ce) (Ce,Ca,Th)(P,Si)O4 P 21/n 2/m |
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38.4.3.4 Brabantite CaTh(PO4)2 P 21 2 |
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38.4.3.5 Monazite-(Nd) (Nd,Ce,La)(P,Si)O4 P 21/n 2/m |
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38.4.3.6 Gasparite-(Ce) CeAsO4 P 21/n 2/m |
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38.4.3.7 Monazite-(Sm) ! SmPO4 P 21/n 2/m |
Strunz Class: |
VII/A.15-35 VII - Phosphates, Arsenates and Vanadates |
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VII/A - Waterfree phosphates [PO4]3- without unfamiliar anions, cations of very big size: Ca, Na and andre |
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VII/A.15 - Monazite group |
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VII/A.15-10 Monazite-(La) (La,Ce,Nd)PO4 P 21/n 2/m |
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VII/A.15-20 Monazite-(Ce) (Ce,La,Nd,Th)PO4 P 21/n 2/m |
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VII/A.15-30 Monazite-(Nd) (Nd,Ce,La)(P,Si)O4 P 21/n 2/m |
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VII/A.15-35 Monazite-(Sm) SmPO4 P 21/n 2/m |
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VII/A.15-40 Cheralite-(Ce) (Ce,Ca,Th)(P,Si)O4 P 21/n 2/m |
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VII/A.15-50 Brabantite CaTh(PO4)2 P 21 2 |
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Other Monazite-(Sm) Information
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References: |
NAME( CanMin, v 41, p 820) PHYS. PROP.(CanMin, v 41, p 820) OPTIC PROP.(CanMin, v 41, p 820) |
See Also: |
Links to other databases for Monazite-(Sm) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -MinDAT
6 -MinMax(Deutsch)
7 -MinMax(English)
8 -Mineralienatlas (Deutsch)
9 -QUT Mineral Atlas
10 - Uranium Minerals
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Print or Cut-and-Paste your Monazite-(Sm) Specimen Label here :
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Monazite-(Sm)
SmPO4
Dana No: 38.4.3.7 Strunz No: VII/A.15-35
Locality:
Notes:
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