General Ludwigite Information
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Chemical Formula: |
Mg2Fe+++BO5 |
Composition: |
Molecular Weight = 195.26 gm |
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Magnesium 24.89 % Mg 41.28 % MgO |
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Iron 28.60 % Fe 40.89 % Fe2O3 |
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Boron 5.54 % B 17.83 % B2O3 |
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Oxygen 40.97 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Mg2Fe3+BO5 |
Environment: |
Typically formed in a magnesian iron skarn and contact metamorphic deposits. Forms a series with vonsenite. |
IMA Status: |
Valid Species (Pre-IMA) 1874 |
Locality: |
Ocna de Fier (Vaskö, Morávica, Eisenstein), Banat, Romania Link to MinDat.org Location Data. |
Name Origin: |
Named after the Austrian chemist, Ernst Ludwig (1842-1915). |
Synonym: |
ICSD 65435 |
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Magnesioludwighite |
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PDF 46-1290 |
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Ludwigite Image |
Images:
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Ludwigite
Comments: Limonitic matrix with blue crystals of ludwigite.
Location: Simms Pass, Lemhi County, Idaho, USA.
Scale: Crystal size 9 mm.
© John Veevaert |
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Images:
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Images:
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Ludwigite
Comments: Bright black, radial fibrous aggregates of ludwigite.
Location: Brosso mine, Piemonte, Italy.
Scale: Sample size 4x3 cm.
© Minernet |
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Ludwigite Crystallography
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Axial Ratios: |
a:b:c =0.7553:1:0.2487 |
Cell Dimensions: |
a = 9.26, b = 12.26, c = 3.05, Z = 4; V = 346.26 Den(Calc)= 3.75 |
Crystal System: |
Orthorhombic - DipyramidalH-M Symbol (2/m 2/m 2/m) Space Group: Pbam |
X Ray Diffraction: |
By Intensity(I/Io): 5.12(1), 2.515(0.7), 2.547(0.7), |
Crystal Structure:
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Help on Above
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Irwin M B , Peterson R C , The Canadian Mineralogist , 37 (1999) p.939-943, The crystal structure of ludwigite, Locality: Crestmore quarry, California, USA
View Additional jPOWD Structure files for Ludwigite
[1]
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Physical Properties of Ludwigite
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Cleavage: |
[001] Perfect |
Color: |
Dark green, Black, Black green. |
Density: |
3.7 - 4, Average = 3.85 |
Diaphaniety: |
Opaque to subtranslucent |
Fracture: |
Brittle - Conchoidal - Very brittle fracture producing small, conchoidal fragments. |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Massive - Fibrous - Distinctly fibrous fine-grained forms. |
Habit: |
Radial - Crystals radiate from a center without producing stellar forms (e.g. stibnite) |
Hardness: |
5.5 - Knife Blade |
Luminescence: |
None. |
Luster: |
Silky |
Streak: |
greenish black |
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Optical Properties of Ludwigite
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Gladstone-Dale: |
CI meas= 0.062 (Fair) - where the CI = (1-KPDmeas/KC) CI calc= 0.037 (Excellent) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2404,KPDmeas= 0.2342,KC= 0.2497 |
Optical Data: |
Biaxial (+), a=1.83-1.85, b=1.83-1.9, g=1.97-2.03, bire=0.1400-0.1800, 2V(Calc)=0-68, 2V(Meas)=Small. Dispersion r >> v extreme. |
Pleochroism (x): |
dark green. |
Pleochroism (y): |
dark green. |
Pleochroism (z): |
dark reddish brown. |
RL Anisotrophism: |
Strong, yellowish brown to bluish violet gray. |
RL Bireflectance: |
Pinkish gray to dark greenish gray. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Ludwigite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
10.10 |
13.80 |

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| 420 nm |
9.70 |
13.20 |

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| 440 nm |
9.30 |
12.60 |

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| 460 nm |
9.00 |
12.10 |

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| 480 nm |
8.70 |
11.80 |

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| 500 nm |
8.50 |
11.50 |

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| 520 nm |
8.20 |
11.30 |

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| 540 nm |
8.10 |
11.20 |

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| 560 nm |
7.90 |
11.00 |

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| 580 nm |
7.80 |
10.90 |

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| 600 nm |
7.60 |
10.80 |

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| 620 nm |
7.50 |
10.80 |

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| 640 nm |
7.40 |
10.80 |

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| 660 nm |
7.30 |
10.80 |

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| 680 nm |
7.20 |
10.80 |

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| 700 nm |
7.20 |
10.90 |

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Calculated Relative Intensity Colors of Ludwigite in Air
Relative Intensity |
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1000% |
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Calculated Properties of Ludwigite
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Electron Density: |
relectron=3.65 gm/cc note: rLudwigite =3.75 gm/cc. |
Fermion Index |
Fermion Index = 0.04217 Boson Index = 0.95783 |
Photoelectric: |
PELudwigite = 9.17 barns/electron U=PELudwigite x relectron= 33.46 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Ludwigite is Not Radioactive |
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Ludwigite Classification
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Dana Class: |
24.2.1.1 (24)Borates - Anhydrous |
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(24.2)where (A)2 BO2 [XO3] |
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(24.2.1)Ludwigite Group (Space Group: Pbam) |
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24.2.1.1 Ludwigite Mg2FeBO5 Pbam 2/m 2/m 2/m |
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24.2.1.2 Vonsenite Fe2FeBO5 Pbam 2/m 2/m 2/m |
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24.2.1.3 Azoproite (Mg,Fe)2(Fe,Ti,Mg)BO5 Pbam 2/m 2/m 2/m |
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24.2.1.4 Bonaccordite Ni2FeBO5 Pbam 2/m 2/m 2/m |
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24.2.1.5 Chestermanite Mg2(Fe,Mg,Al,Sb)BO3O2 Pbam 2/m 2/m 2/m |
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24.2.1.6 Fredrikssonite Mg2(Mn,Fe)O2(BO3) Pbam 2/m 2/m 2/m |
Strunz Class: |
V/G.04-10 V - Nitrates, Carbonates and Borates |
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V/G - "Insel" borates [BO3]3- "inseln" |
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V/G.04 - Ludwigite group |
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V/G.04-10 Ludwigite Mg2FeBO5 Pbam 2/m 2/m 2/m |
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V/G.04-20 Vonsenite Fe2FeBO5 Pbam 2/m 2/m 2/m |
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V/G.04-30 Azoproite (Mg,Fe)2(Fe,Ti,Mg)BO5 Pbam 2/m 2/m 2/m |
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V/G.04-40 Chestermanite Mg2(Fe,Mg,Al,Sb)BO3O2 Pbam 2/m 2/m 2/m |
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V/G.04-50 Fredrikssonite Mg2(Mn,Fe)O2(BO3) Pbam 2/m 2/m 2/m |
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V/G.04-60 Bonaccordite Ni2FeBO5 Pbam 2/m 2/m 2/m |
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V/G.04-70 Takeuchiite Mg2MnO2(BO3) Pnnm 2/m 2/m 2/m |
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V/G.04-80 Orthopinakiolite (Mg,Mn)2MnBO5 Pnnm 2/m 2/m 2/m |
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V/G.04-90 Blatterite (Mn,Mg)35Sb3(Mn,Fe)9(BO3)16O32 Pnnm 2/m 2/m 2/m |
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V/G.04-100 Gaudefroyite Ca4Mn3-x(BO3)3(CO3)(O,OH)3 P 63 6 |
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Other Ludwigite Information
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References: |
NAME( AntBidBlaNic5) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic5) |
See Also: |
Links to other databases for Ludwigite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 - Scandinavian mineral gallery
14 - WWW-MINCRYST
15 -École des Mines de Paris
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Print or Cut-and-Paste your Ludwigite Specimen Label here :
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Ludwigite
Mg2Fe+++BO5
Dana No: 24.2.1.1 Strunz No: V/G.04-10
Locality:
Notes:
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