General Gramaccioliite-(Y) Information
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Chemical Formula: |
(Pb,Sr)(Y,Mn)Fe2(Ti,Fe)18O38 |
Composition: |
Molecular Weight = 1,822.46 gm |
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Barium 0.15 % Ba 0.17 % BaO |
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Strontium 1.30 % Sr 1.54 % SrO |
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Calcium 0.09 % Ca 0.12 % CaO |
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Lanthanum 0.15 % La 0.18 % La2O3 |
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Cerium 0.62 % Ce 0.72 % Ce2O3 |
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Yttrium 2.39 % Y 3.04 % Y2O3 |
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Uranium 0.26 % U 0.29 % U2O3 |
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Titanium 35.55 % Ti 59.30 % TiO2 |
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Manganese 1.12 % Mn 1.44 % MnO |
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Niobium 0.20 % Nb 0.29 % Nb2O5 |
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Vanadium 0.11 % V 0.20 % V2O5 |
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Zinc 0.79 % Zn 0.98 % ZnO |
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Iron 16.82 % Fe 21.64 % FeO |
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Lead 6.94 % Pb 7.47 % PbO |
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Neodymium 0.16 % Nd 0.18 % Nd2O3 |
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Oxygen 33.36 % O |
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______ ______ |
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100.00 % 97.56 % = TOTAL OXIDE |
Empirical Formula: |
Pb0.61Sr0.27Ba0.02U0.02Y0.49Mn2+0.37Ce0.08Ca0.04Nd0.02La0.02Ti13.53Fe2+5.49Zn0.22
V5+0.04Nb0.04O38 |
Environment: |
Hydrothermal quartz veins in a biotitic gneiss. (crichtonite group; structure) |
IMA Status: |
Approved IMA 2003 (Dana # Added) |
Locality: |
Sambuco, Stura Valley, Piedmont, Italy. Link to MinDat.org Location Data. |
Name Origin: |
Named for Prof. Carlo M. Gramaccioli (1935-) of the University of Milano, Italy. |
Synonym: |
Davidite-(Y) |
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IMA2001-034 |
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Images:
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Gramaccioliite-(Y) Crystallography
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Axial Ratios: |
a:c = 1:2.01421 |
Cell Dimensions: |
a = 10.411, c = 20.97, Z = 3; V = 1,968.40 Den(Calc)= 4.61 |
Crystal System: |
Trigonal - RhombohedralH-M Symbol ( 3) Space Group: R 3 |
X Ray Diffraction: |
By Intensity(I/Io): 3.002(1)(300), 1.606(0.95)(3.1.10), 2.258(0.7)(134),2.892(0.7)(116), 1.809(0.6)(318), 2.147(0.5), 2.852(0.5), |
Crystal Structure:
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Orlandi P , Pasero M , Rotiroti N , Olmi F , Demartin F , Moelo Y , European Journal of Mineralogy , 16 (2004) p.171-175, Gramaccioliite-(Y), a new mineral of the crichtonite group from Stura Valley, Piedmont, Italy, Locality: the gneiss of the Hercynian Massif of Argentera at Sambuco, Italy
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Physical Properties of Gramaccioliite-(Y)
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Cleavage: |
None |
Color: |
Black. |
Diaphaniety: |
Opaque |
Fracture: |
Brittle - Conchoidal - Very brittle fracture producing small, conchoidal fragments. |
Habit: |
Hexagonal - Six-sided crystal shape in cross-section or habit. |
Habit: |
Tabular - Form dimensions are thin in one direction. |
Luster: |
Metallic |
Streak: |
black |
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Optical Properties of Gramaccioliite-(Y)
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Optical Data: |
NCalc= 2.38 - from Gladstone-Dale relationship (KC = 0.2989) where Ncalc=Dcalc*KC+1 |
RL Anisotrophism: |
Weak. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Gramaccioliite-(Y) in Air
| λ |
R |
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∑ R(λ) |
| 470 nm |
19.20 |
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| 546 nm |
17.90 |
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| 589 nm |
17.60 |
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| 650 nm |
17.40 |
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Standardized Intensity (100%) Reflection Spectra of Gramaccioliite-(Y) in Oil
| λ |
R |
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∑ R(λ) |
| 470 nm |
6.70 |
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| 546 nm |
5.90 |
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| 589 nm |
5.70 |
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| 650 nm |
5.80 |
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Calculated Relative Intensity Colors of Gramaccioliite-(Y) in Air
Relative Intensity |
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350% |
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450% |
500% |
| R |
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Calculated Relative Intensity Colors of Gramaccioliite-(Y) in Oil
Relative Intensity |
0% |
100% |
200% |
300% |
400% |
500% |
600% |
700% |
800% |
900% |
1000% |
| R |
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Calculated Properties of Gramaccioliite-(Y)
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Electron Density: |
relectron=4.32 gm/cc note: rGramaccioliite-(Y) =4.61 gm/cc. |
Fermion Index |
Fermion Index = 0.06686 Boson Index = 0.93314 |
Photoelectric: |
PEGramaccioliite-(Y) = 142.11 barns/electron U=PEGramaccioliite-(Y) x relectron= 613.22 barns/cc. |
Radioactivity: |
GRapi = 21,765.13 (Gamma Ray American Petroleum Institute Units)
Gramaccioliite-(Y) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Radioactivity from Gramaccioliite-(Y) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.45 cm |
488,303 |
1.32E-05 |
21,765.13 |
7.16 |
| 100 gm / 3.46 cm |
48,830 |
1.32E-06 |
2,176.51 |
0.72 |
| 10 gm / 1.61 cm |
4,883 |
1.32E-07 |
217.65 |
0.07 |
| 1 gm / 7.45 mm |
488 |
1.32E-08 |
21.77 |
0.01 |
| 0.1 gm / 3.46 mm |
49 |
1.32E-09 |
2.18 |
0.00 |
| 0.01 gm / 1.61 mm |
5 |
1.32E-10 |
0.22 |
0.00 |
| 0.001 gm / 0.75 mm |
0 |
1.32E-11 |
0.02 |
0.00 |
Weight of pure Gramaccioliite-(Y) in grams (gm) and Calculated Diameter of a Sphere with a Density of 4.61 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 0.05 % Th) From Sum REE Elements ( 0.93 % REE)
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Gramaccioliite-(Y) Classification
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Dana Class: |
8.5.1.11 (8)Multiple Oxides with Nb, Ta, and Ti |
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(8.5)Dana Type |
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(8.5.1)Crichtonite group (ABC18 T2 O38) |
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8.5.1.1 Landauite NaMnZn2(Ti,Fe)6Ti12O38 R 3 3 |
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8.5.1.2 Loveringite (Ca,Ce)(Ti,Fe,Cr,Mg)21O38 R 3 3 |
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8.5.1.3 Crichtonite (Sr,La,Ce,Y)(Ti,Fe,Mn)21O38 R 3 3 |
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8.5.1.4 Senaite Pb(Ti,Fe,Mn)21O38 R 3 3 |
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8.5.1.5 Davidite-(La) (La,Ce,Ca)(Y,U)(Ti,Fe)20O38 R 3 3 |
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8.5.1.6 Davidite-(Ce) (Ce,La)(Y,U)(Ti,Fe)20O38 R 3 3 |
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8.5.1.7 Mathiasite (K,Ca,Sr)(Ti,Cr,Fe,Mg)21O38 R 3 3 |
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8.5.1.8 Lindsleyite (Ba,Sr)(Ti,Cr,Fe,Mg)21O38 R 3 3 |
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8.5.1.9 Dessauite! (Sr,Pb)(Y,U)(Ti,Fe)20O38 P 3 3 |
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8.5.1.10 Cleusonite! Pb(U,U)(Ti,Fe2,Fe3)20(O,OH)38 R 3 3 |
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8.5.1.11 Gramaccioliite-(Y) ! (Pb,Sr)(Y,Mn)Fe2(Ti,Fe)18O38 R 3 3 |
Strunz Class: |
IV/C.09-62 IV - Oxides |
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IV/C - Oxides with metal : oxygen = 2:3 (M2O3 and related compounds) |
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IV/C.09 - Crichtonite group |
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IV/C.09-10 Landauite NaMnZn2(Ti,Fe)6Ti12O38 R 3 3 |
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IV/C.09-20 Mathiasite (K,Ca,Sr)(Ti,Cr,Fe,Mg)21O38 R 3 3 |
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IV/C.09-30 Loveringite (Ca,Ce)(Ti,Fe,Cr,Mg)21O38 R 3 3 |
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IV/C.09-40 Crichtonite (Sr,La,Ce,Y)(Ti,Fe,Mn)21O38 R 3 3 |
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IV/C.09-45 Dessauite! (Sr,Pb)(Y,U)(Ti,Fe)20O38 P 3 3 |
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IV/C.09-50 Lindsleyite (Ba,Sr)(Ti,Cr,Fe,Mg)21O38 R 3 3 |
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IV/C.09-60 Davidite-(La) (La,Ce,Ca)(Y,U)(Ti,Fe)20O38 R 3 3 |
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IV/C.09-62 Gramaccioliite-(Y) (Pb,Sr)(Y,Mn)Fe2(Ti,Fe)18O38 R 3 3 |
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IV/C.09-70 Davidite-(Ce) (Ce,La)(Y,U)(Ti,Fe)20O38 R 3 3 |
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IV/C.09-80 Senaite Pb(Ti,Fe,Mn)21O38 R 3 3 |
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Other Gramaccioliite-(Y) Information
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References: |
NAME( AmMin 89:1827) PHYS. PROP.(AmMin 89:1827) OPTIC PROP.(AmMin 89:1827) |
See Also: |
Links to other databases for Gramaccioliite-(Y) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -MinDAT
6 -MinMax(Deutsch)
7 -MinMax(English)
8 -Mineralienatlas (Deutsch)
9 -QUT Mineral Atlas
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Print or Cut-and-Paste your Gramaccioliite-(Y) Specimen Label here :
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Gramaccioliite-(Y)
(Pb,Sr)(Y,Mn)Fe2(Ti,Fe)18O38
Dana No: 8.5.1.11 Strunz No: IV/C.09-62
Locality:
Notes:
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