General Ferricopiapite Information
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Chemical Formula: |
Fe+++2/3Fe+++4(SO4)6(OH)2·20(H2O) |
Composition: |
Molecular Weight = 1,231.32 gm |
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Iron 21.17 % Fe 30.26 % Fe2O3 |
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Hydrogen 3.44 % H 30.72 % H2O |
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Sulfur 15.63 % S 39.01 % SO3 |
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Oxygen 59.77 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Fe3+0.6666Fe3+4(SO4)6(OH)2·20(H2O) |
IMA Status: |
Valid Species (Pre-IMA) 1938 |
Locality: |
Link to MinDat.org Location Data. |
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Ferricopiapite Image |
Images:
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Images:
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Ferricopiapite Crystallography
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Axial Ratios: |
a:b:c =0.4027:1:0.3989 |
Cell Dimensions: |
a = 7.394, b = 18.36, c = 7.324, Z = 1; alpha = 93.8°, beta = 102.2°, gamma = 98.9° V = 958.00 Den(Calc)= 2.13 |
Crystal System: |
Triclinic - PinacoidalH-M Symbol ( 1) Space Group: P1 |
X Ray Diffraction: |
By Intensity(I/Io): 9.06(1), 3.58(0.8), 5.58(0.8), |
Crystal Structure:
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Majzlan J , Navrotsky A , McCleskey R B , Alpers C N , European Journal of Mineralogy , 18 (2006) p.175-186, Thermodynamic properties and crystal structure refinement of, ferricopiapite, coquimbite, rhomboclase, and Fe2(SO4)3(H2O)5, Locality: synthetic
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Physical Properties of Ferricopiapite
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Cleavage: |
[???] Perfect |
Color: |
Yellow, Orange. |
Density: |
2.1 |
Diaphaniety: |
Transparent to Translucent |
Hardness: |
2.5-3 - Finger Nail-Calcite |
Luster: |
Pearly |
Streak: |
light yellow |
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Optical Properties of Ferricopiapite
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Gladstone-Dale: |
CI meas= -0.058 (Good) - where the CI = (1-KPDmeas/KC) CI calc= -0.043 (Good) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2805,KPDmeas= 0.2845,KC= 0.2688 |
Optical Data: |
Biaxial (+), a=1.575, g=1.62, bire=0.0450, 2V(Meas)=74. |
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Calculated Properties of Ferricopiapite
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Electron Density: |
relectron=2.17 gm/cc note: rFerricopiapite =2.13 gm/cc. |
Fermion Index |
Fermion Index = 0.00595 Boson Index = 0.99405 |
Photoelectric: |
PEFerricopiapite = 7.09 barns/electron U=PEFerricopiapite x relectron= 15.39 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Ferricopiapite is Not Radioactive |
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Ferricopiapite Classification
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Dana Class: |
31.10.5.4 (31)Hydrated Sulfates Containing Hydroxyl or Halogen |
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(31.10)miscellaneous |
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(31.10.5)Copiapite Group |
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31.10.5.1 Copiapite FeFe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.2 Magnesiocopiapite MgFe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.3 Cuprocopiapite CuFe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.4 Ferricopiapite Fe2/3Fe4(SO4)6(OH)2·20(H2O) P1 1 |
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31.10.5.5 Calciocopiapite CaFe4(SO4)6(OH)2·19(H2O) P1 1 |
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31.10.5.6 Zincocopiapite ZnFe4(SO4)6(OH)2·18(H2O) P1 1 |
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31.10.5.7 Aluminocopiapite Al2/3Fe4(SO4)6O(OH)2·20(H2O) P1 1 |
Strunz Class: |
VI/D.10-90 VI - Sulfates,Chromates,Molybdates and Tungstates |
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VI/D - Water-bearing sulfates with unfamiliar anions. cations of medium size |
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VI/D.10 - Copiapite group, Botryogen - Chaidamuite |
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VI/D.10-10 Botryogen MgFe(SO4)2(OH)·7(H2O) P 21/n 2/m |
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VI/D.10-20 Zincobotryogen (Zn,Mg,Mn)Fe(SO4)2(OH)·7(H2O) P 21/n 2/m |
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VI/D.10-30 Calciocopiapite CaFe4(SO4)6(OH)2·19(H2O) P1 1 |
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VI/D.10-40 Magnesiocopiapite MgFe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-50 Copiapite FeFe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-60 Cuprocopiapite CuFe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-70 Zincocopiapite ZnFe4(SO4)6(OH)2·18(H2O) P1 1 |
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VI/D.10-80 Aluminocopiapite Al2/3Fe4(SO4)6O(OH)2·20(H2O) P1 1 |
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VI/D.10-90 Ferricopiapite Fe2/3Fe4(SO4)6(OH)2·20(H2O) P1 1 |
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VI/D.10-100 Guildite CuFe(SO4)2(OH)·4(H2O) P 21/m 2/m |
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VI/D.10-110 Chaidamuite (Zn,Fe)Fe(SO4)2(OH)·4(H2O) P1 1 |
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Other Ferricopiapite Information
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References: |
PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Ferricopiapite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 -École des Mines de Paris
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Ferricopiapite
Fe+++2/3Fe+++4(SO4)6(OH)2·20(H2O)
Dana No: 31.10.5.4 Strunz No: VI/D.10-90
Locality:
Notes:
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