General Coskrenite-(Ce) Information
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Chemical Formula: |
(Ce,Nd,La)2(SO4)2(C2O4)·8(H2O) |
Composition: |
Molecular Weight = 706.61 gm |
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Lanthanum 5.90 % La 6.92 % La2O3 |
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Cerium 21.81 % Ce 25.55 % Ce2O3 |
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Hydrogen 2.28 % H 20.40 % H2O |
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Carbon 3.40 % C 10.19 % C2O3 |
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Sulfur 9.08 % S 22.66 % SO3 |
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Neodymium 12.25 % Nd 14.29 % Nd2O3 |
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Oxygen 45.28 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Ce1.1Nd0.6La0.3(SO4)2(C2O4)·8(H2O) |
Environment: |
Associated with epsomite and "hair salts" in soil sheltered by an overhanging bluff. The sulfate is from the oxidation of pyritiferous shales in the bedrock. |
IMA Status: |
Approved IMA 1996 (Dana # Added) |
Locality: |
Alum Cave Bluff, Tennessee, USA. Link to MinDat.org Location Data. |
Name Origin: |
Named for T. Dennis Coskren (1942-), geologist from Columbia, Maryland, whose work was instrumental in the discovery to the mineral. |
Synonym: |
IMA1996-056 |
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Coskrenite-(Ce) Crystallography
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Axial Ratios: |
a:b:c =0.476:1:0.7168 |
Cell Dimensions: |
a = 8.718, b = 18.313, c = 13.128, Z = 6; beta = 94° V = 2,090.82 Den(Calc)= 3.37 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/c |
X Ray Diffraction: |
By Intensity(I/Io): 5.48(1)(110), 8.52(0.7)(001), 3.84(0.6)(020,110),6.72(0.6)(011), 4.26(0.5)(002,012), 2.744(0.4)(122,212 |
Crystal Structure:
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Peacor D R , Rouse R C , Essene E J , Lauf R J , The Canadian Mineralogist , 37 (1999) p.1453-1462, Coskrenite-(Ce), (Ce,Nd,La)2(SO4)2(C2O4).8H2O, a new rare-earth oxalate mineral, from Alum Cave Bluff, Tennessee: Characterization and crystal structure, Locality: Alum Cave Bluff, Tennessee, USA
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Physical Properties of Coskrenite-(Ce)
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Cleavage: |
[001] Perfect |
Color: |
Pink, Very pale blue, Cream. |
Diaphaniety: |
Transparent |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Habit: |
Tabular - Form dimensions are thin in one direction. |
Habit: |
Water Soluble - Water soluble mineral. |
Habit: |
Wedge shaped - Crystals shaped like a wedge. |
Luminescence: |
Non-fluorescent, Short UV=very pale blue, Long UV=very pale blue. |
Luster: |
Vitreous (Glassy) |
Streak: |
white |
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Optical Properties of Coskrenite-(Ce)
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Gladstone-Dale: |
CI calc= 0.031 (Excellent) - where the CI = (1-KPDcalc/KC) KPDcalc= 0.1705,KC= 0.1761 |
Optical Data: |
Biaxial (-), a=1.544, b=1.578, g=1.602, bire=0.0580, 2V(Calc)=78, 2V(Meas)=65. Dispersion medium, r > v. |
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Calculated Properties of Coskrenite-(Ce)
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Electron Density: |
relectron=3.21 gm/cc note: rCoskrenite-(Ce) =3.37 gm/cc. |
Fermion Index |
Fermion Index = 0.02641 Boson Index = 0.97359 |
Photoelectric: |
PECoskrenite-(Ce) = 200.21 barns/electron U=PECoskrenite-(Ce) x relectron= 643.37 barns/cc. |
Radioactivity: |
GRapi = 40,641.89 (Gamma Ray American Petroleum Institute Units)
Coskrenite-(Ce) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
748.41 ±187.10 grams of pure Coskrenite-(Ce) .
Estimated Radioactivity from Coskrenite-(Ce) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 8.28 cm |
895,041 |
2.42E-05 |
40,641.89 |
13.36 |
| 100 gm / 3.84 cm |
89,504 |
2.42E-06 |
4,064.19 |
1.34 |
| 10 gm / 1.78 cm |
8,950 |
2.42E-07 |
406.42 |
0.13 |
| 1 gm / 8.28 mm |
895 |
2.42E-08 |
40.64 |
0.01 |
| 0.1 gm / 3.84 mm |
90 |
2.42E-09 |
4.06 |
0.00 |
| 0.01 gm / 1.78 mm |
9 |
2.42E-10 |
0.41 |
0.00 |
| 0.001 gm / 0.83 mm |
1 |
2.42E-11 |
0.04 |
0.00 |
Weight of pure Coskrenite-(Ce) in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.37 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 2.00 % Th) From Sum REE Elements (39.96 % REE)
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Coskrenite-(Ce) Classification
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Dana Class: |
50.1.9.2 (50)Salts of Organic Acids |
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(50.1)(Oxalates) |
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(50.1.9)Dana Group |
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50.1.9.1 Zugshunstite-(Ce)! (Ce,Nd,La)Al(SO4)2(C2O4)·8(H2O) C 2/c 2/m |
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50.1.9.2 Coskrenite-(Ce) ! (Ce,Nd,La)2(SO4)2(C2O4)·8(H2O) C 2/c 2/m |
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50.1.9.3 Levinsonite-(Y)! (Y,Nd,La)Al(SO4)2(C2O4)·12(H2O) P 2/n 2/m |
Strunz Class: |
IX/A.01-110 IX - Organic compunds |
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IX/A - Oxalates. Salts from organic acids. [C2O4]2- arranged after increasing cation size |
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IX/A.01 - Whewellite - Wheatleyite series |
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IX/A.01-05 Natroxalate! Na2C2O4 P 21/a 2/m |
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IX/A.01-10 Whewellite Ca(C2O4)·(H2O) P 21/n 2/m |
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IX/A.01-20 Weddellite Ca(C2O4)·2(H2O) I 4/m 4/m |
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IX/A.01-25 Caoxite! Ca(C2O4)·3(H2O) P1 1 |
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IX/A.01-28 Novgorodovaite! Ca2(C2O4)Cl2·2(H2O) I2/m 2/m |
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IX/A.01-30 Oxammite (NH4)2(C2O4)·(H2O) P 21212 2 2 2 |
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IX/A.01-40 Glushinskite Mg(C2O4)·2(H2O) C 2/c 2/m |
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IX/A.01-50 Humboldtine Fe(C2O4)·2(H2O) I2/a 2/m |
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IX/A.01-55 Lindbergite! Mn(C2O4)·2(H2O) C 2/c 2/m |
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IX/A.01-60 Minguzzite K3Fe(C2O4)3·3(H2O) P 21/c 2/m |
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IX/A.01-70 Zhemchuzhnikovite NaMg(Al,Fe)(C2O4)3·8(H2O) Unk Trig |
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IX/A.01-80 Stepanovite NaMgFe(C2O4)3·8-9(H2O) Unk Trig |
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IX/A.01-90 Moolooite Cu(C2O4)·n(H2O)(n<1) Unk Ortho |
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IX/A.01-100 Wheatleyite Na2Cu(C2O4)2·2(H2O) P1 1 |
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IX/A.01-110 Coskrenite-(Ce) (Ce,Nd,La)2(SO4)2(C2O4)·8(H2O) C 2/c 2/m |
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IX/A.01-120 Levinsonite-(Y)! (Y,Nd,La)Al(SO4)2(C2O4)·12(H2O) P 2/n 2/m |
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IX/A.01-130 Zugshunstite-(Ce)! (Ce,Nd,La)Al(SO4)2(C2O4)·8(H2O) C 2/c 2/m |
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Other Coskrenite-(Ce) Information
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References: |
NAME( AmMin, vol 85, p1561) PHYS. PROP.(AmMin, vol 85, p1561) OPTIC PROP.(AmMin, vol 85, p1561) |
See Also: |
Links to other databases for Coskrenite-(Ce) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 -Google Images
4 -Google Scholar
5 -Handbook of Mineralogy (UofA)
6 -MinDAT
7 -MinMax(Deutsch)
8 -MinMax(English)
9 -Mineralienatlas (Deutsch)
10 -QUT Mineral Atlas
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Print or Cut-and-Paste your Coskrenite-(Ce) Specimen Label here :
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Coskrenite-(Ce)
(Ce,Nd,La)2(SO4)2(C2O4)·8(H2O)
Dana No: 50.1.9.2 Strunz No: IX/A.01-110
Locality:
Notes:
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