Willhendersonite Mineral Data

Willhendersonite Mineral Data +

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General Willhendersonite Information

Chemical Formula:

KCaAl3Si3O12·5(H2O)

Composition:

Molecular Weight = 526.45 gm

Potassium 7.43 % K 8.95 % K₂O

Calcium 7.61 % Ca 10.65 % CaO

Aluminum 15.38 % Al 29.05 % Al₂O₃

Silicon 16.00 % Si 34.24 % SiO₂

Hydrogen 1.91 % H 17.11 % H₂O

Oxygen 51.67 % O

______ ______

100.00 % 100.00 % = TOTAL OXIDE

Empirical Formula:

KCaAl₃Si₃O₁₂·5(H₂O)

IMA Status:

Approved IMA 1984

Locality:

San Venanzo quarry, Terni, Umbria, Italy. Link to MinDat.org Location Data.

Name Origin:

Named after William A. Henderson, of Stamford, Connecticut, U.S.A., who noted this as an unusual mineral and provided it for study.

Synonym:

ICSD 30873

PDF 35-643

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Willhendersonite Crystallography

Axial Ratios:

a:b:c =0.9989:1:1.0308

Cell Dimensions:

a = 9.206, b = 9.216, c = 9.5, Z = 2; alpha = 92.34°, beta = 92.7°, gamma = 90.12° V = 804.44 Den(Calc)= 2.17

Crystal System:

Triclinic - PinacoidalH-M Symbol ( 1) Space Group: P1

$Help on X Ray Diffraction:$ X Ray Diffraction:

By Intensity(I/I_o): 9.16(1), 2.907(0.6), 2.804(0.5),

Crystal Structure:

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Tillmanns E , Fischer R X , Baur W H , Neues Jahrbuch fur Mineralogie, Monatshefte , 1984 (1984) p.547-558, Chabazite-type framework in the new zeolite willhendersonite,, KCaAl3O12*5H2O

Physical Properties of Willhendersonite

Cleavage:

[100] Perfect, [010] Perfect, [001] Perfect

Color:

Colorless.

Density:

2.18

Diaphaniety:

Transparent

Hardness:

3 - Calcite

Luster:

Vitreous (Glassy)

Streak:

white

Optical Properties of Willhendersonite

Gladstone-Dale:

CI meas= -0.022 (Excellent) - where the CI = (1-KPDmeas/KC)
CI calc= -0.026 (Excellent) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2355,KPDmeas= 0.2344,KC= 0.2294

Optical Data:

Biaxial (?), a=1.505, b=1.511, g=1.517, bire=0.0120, 2V(Calc)=88, 2V(Meas)=87.

Calculated Properties of Willhendersonite

Electron Density:

r_electron=2.20 gm/cc
note: r_{Willhendersonite}=2.18 gm/cc.

Fermion Index

Fermion Index = 0.00783
Boson Index = 0.99217

Photoelectric:

PE_{Willhendersonite}= 2.75 barns/electron
U=PE_{Willhendersonite} x r_electron= 6.07 barns/cc.

Radioactivity:

GRapi = 108.27 (Gamma Ray American Petroleum Institute Units)

Estimated Radioactivity from Willhendersonite - barely detectable

Willhendersonite Classification

Dana Class:

77.1.2.3 (77)Tectosilicate Zeolite group

(77.1)true zeolites

(77.1.2)Chabazite and related species

77.1.2.1 Chabazite-Ca (Ca0.5,Na,K)4[Al4Si8O24]·12H2O P1 1

77.1.2.1a Chabazite-Na! (Na2,K2,Ca,Mg)[Al2Si4O12]·6(H2O) R 3m 3 2/m

77.1.2.1b Chabazite-K! (K2,Ca,Na2,Mg)[Al2Si4O12]·6(H2O) R 3m 3 2/m

77.1.2.1c Chabazite-Sr! (Sr,Ca,K2,Na2)[Al2Si4O12]·6(H2O) R 3m 3 2/m

77.1.2.2 Herschelite? (Na,Ca,K)AlSi2O6·3(H2O) R 3m 3 2/m

77.1.2.3 Willhendersonite KCaAl3Si3O12·5(H2O) P1 1

77.1.2.4 Offretite (K2,Ca,Mg)2.5Al5Si13O36·15(H2O) P 6m2 6 m2

77.1.2.5 Erionite-Na (Na2,K2,Ca)2[Al4Si14O36]·15(H2O) P 6₃/mmc 6/m 2/m 2/m

77.1.2.5a Erionite-K! (K2,Ca,Na2)2[Al4Si14O36]·15(H2O) P 6₃/mmc 6/m 2/m 2/m

77.1.2.5b Erionite-Ca! (Ca,K2,Na2)2[Al4Si14O36]·15(H2O) P 6₃/mmc 6/m 2/m 2/m

77.1.2.6 Gmelinite-Na (Na2,Ca)Al2Si4O12·6(H2O) P 6₃/mmc 6/m 2/m 2/m

77.1.2.6a Gmelinite-Ca! (Ca,Na2)Al2Si4O12·6(H2O) P 6₃/mmc 6/m 2/m 2/m

77.1.2.6b Gmelinite-K! (K,Na,Ca)6(Al7Si17O48)·22(H2O) P 6₃/mmc 6/m 2/m 2/m

77.1.2.7 Faujasite-Na (Na2,Ca,Mg)3.5[Al7Si17O48]·32(H2O) F d3m 4/m 3 2/m

77.1.2.7a Faujasite-Ca! (Ca,Na2,Mg)3.5[Al7Si17O48]·32(H2O) F d3m 4/m 3 2/m

77.1.2.7b Faujasite-Mg! (Mg,Na2,Ca)3.5[Al7Si17O48]·32(H2O) F d3m 4/m 3 2/m

77.1.2.8 Levyne-Ca (Ca,Na2,K2)Al2Si4O12·6(H2O) R 3m 3 2/m

77.1.2.8a Levyne-Na! (Na2,Ca,K2)Al2Si4O12·6(H2O) R 3m 3 2/m

77.1.2.9 Tschortnerite! Ca4(Ca,Sr,K,Ba)3Cu3(OH)8[Si12Al12O48]·x(H2O),x>=20 F m3m 4/m 3 2/m

Strunz Class:

VIII/J.26-10 VIII - Silicates

VIII/J - Tectosilicates (network), with zeolite-structure, Bladed Zeolites

VIII/J.26 - Zeolite group, Willhendersonite - Chabazite - Perialite series

VIII/J.26-10 Willhendersonite KCaAl3Si3O12·5(H2O) P1 1

VIII/J.26-20 Chabazite-Na! (Na2,K2,Ca,Mg)[Al2Si4O12]·6(H2O) R 3m 3 2/m

VIII/J.26-25 Chabazite-K! (K2,Ca,Na2,Mg)[Al2Si4O12]·6(H2O) R 3m 3 2/m

VIII/J.26-30 Chabazite-Ca (Ca0.5,Na,K)4[Al4Si8O24]·12H2O P1 1

VIII/J.26-35 Chabazite-Sr! (Sr,Ca,K2,Na2)[Al2Si4O12]·6(H2O) R 3m 3 2/m

VIII/J.26-40 Tschernichite (Ca,Na)(Si6Al2)O16·4-8(H2O) P 4/mmm 4/m 2/m 2/m

VIII/J.26-50 Gmelinite-Na (Na2,Ca)Al2Si4O12·6(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-52 Gmelinite-K! (K,Na,Ca)6(Al7Si17O48)·22(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-54 Gmelinite-Ca! (Ca,Na2)Al2Si4O12·6(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-58 Levyne-Na! (Na2,Ca,K2)Al2Si4O12·6(H2O) R 3m 3 2/m

VIII/J.26-60 Levyne-Ca (Ca,Na2,K2)Al2Si4O12·6(H2O) R 3m 3 2/m

VIII/J.26-70 Offretite (K2,Ca,Mg)2.5Al5Si13O36·15(H2O) P 6m2 6 m2

VIII/J.26-80 Mazzite K2CaMg2(Al,Si)36O72·28(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-90 Erionite-Na (Na2,K2,Ca)2[Al4Si14O36]·15(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-92 Erionite-K! (K2,Ca,Na2)2[Al4Si14O36]·15(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-94 Erionite-Ca! (Ca,K2,Na2)2[Al4Si14O36]·15(H2O) P 6₃/mmc 6/m 2/m 2/m

VIII/J.26-95 Bellbergite (K,Ba,Sr)2Sr2Ca2(Ca,Na)4Al18Si18O72·30(H2O) P 6₃/mmc, P 6₂c-, P 6₃mc Hex

VIII/J.26-100 Perlialite K8Tl4Al12Si24O72·20(H2O) P 6/mmm 6/m 2/m 2/m

Other Willhendersonite Information

References:

NAME( CanMin, v 35, p 1591) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990)

See Also:

Links to other databases for Willhendersonite :
1 -Am. Min. Crystal Structure Database 2 -Athena 3 - EUROmin Project 4 -Google Images 5 -Google Scholar 6 -Handbook of Mineralogy (MinSocAm) 7 -Handbook of Mineralogy (UofA) 8 -MinDAT 9 -MinMax(Deutsch) 10 -MinMax(English) 11 -Mineralienatlas (Deutsch) 12 -QUT Mineral Atlas 13 -École des Mines de Paris

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Willhendersonite

KCaAl3Si3O12·5(H2O)
Dana No: 77.1.2.3 Strunz No: VIII/J.26-10
Locality:

Notes: