General Vigezzite Information
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Chemical Formula: |
(Ca,Ce)(Nb,Ta,Ti)2O6 |
Composition: |
Molecular Weight = 372.21 gm |
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Calcium 8.61 % Ca 12.05 % CaO |
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Cerium 7.53 % Ce 8.82 % Ce2O3 |
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Tantalum 29.17 % Ta 35.62 % Ta2O5 |
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Titanium 6.43 % Ti 10.73 % TiO2 |
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Niobium 22.46 % Nb 32.14 % Nb2O5 |
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Oxygen 25.79 % O |
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______ ______ |
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100.00 % 99.36 % = TOTAL OXIDE |
Empirical Formula: |
Ca0.8Ce0.2Nb0.9Ta0.6Ti0.5O6 |
Environment: |
Miarolitic cavities in an albitized pegmatite in amphibolite and biotite gneiss. |
IMA Status: |
Approved IMA 1979 |
Locality: |
Orcesco, on Alpe Rosso, Val Vigezzo, Italy. Link to MinDat.org Location Data. |
Name Origin: |
Named for the locality. |
Synonym: |
ICSD 69217 |
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PDF 34-1316 |
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Vigezzite Image |
Images:
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Vigezzite Crystallography
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Axial Ratios: |
a:b:c =0.6854:1:0.486 |
Cell Dimensions: |
a = 7.559, b = 11.028, c = 5.36, Z = 4; V = 446.81 Den(Calc)= 5.53 |
Crystal System: |
Orthorhombic - DipyramidalH-M Symbol (2/m 2/m 2/m) Space Group: Pmnb |
X Ray Diffraction: |
By Intensity(I/Io): 2.974(1), 3.03(1), 4.821(0.9), |
Crystal Structure:
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Giuseppetti G , Tadini P , Neues Jahrbuch fur Mineralogie, Monatshefte , 1990 (1990) p.301-308, The crystal structure of vigezzite, (Ca,Ce)(Nb,Ta,Ti)2O6,, intermediate term of the aeschynite series, Locality: Vigezzo Valley, Novara, Italy
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Physical Properties of Vigezzite
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Cleavage: |
[100] Distinct |
Color: |
Orange, Bright yellow orange. |
Density: |
5.54 |
Diaphaniety: |
Subtranslucent to Opaque |
Fracture: |
Brittle - Conchoidal - Very brittle fracture producing small, conchoidal fragments. |
Habit: |
Euhedral Crystals - Occurs as well-formed crystals showing good external form. |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Habit: |
Striated - Parallel lines on crystal surface or cleavage face. |
Hardness: |
4.5-5 - Near Apatite |
Luster: |
Sub Metallic |
Streak: |
white |
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Optical Properties of Vigezzite
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Gladstone-Dale: |
CI meas= -0.007 (Superior) - where the CI = (1-KPDmeas/KC) CI calc= -0.009 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.222,KPDmeas= 0.2216,KC= 0.2201 |
Optical Data: |
Biaxial (+), a=2.14, g=2.315, bire=0.1750, 2V(Meas)=large. Dispersion extreme. |
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Calculated Properties of Vigezzite
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Electron Density: |
relectron=4.98 gm/cc note: rVigezzite =5.54 gm/cc. |
Fermion Index |
Fermion Index = 0.00859 Boson Index = 0.99141 |
Photoelectric: |
PEVigezzite = 410.44 barns/electron U=PEVigezzite x relectron=2,044.09 barns/cc. |
Radioactivity: |
GRapi = 7,219.41 (Gamma Ray American Petroleum Institute Units)
Vigezzite is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Radioactivity from Vigezzite - mild
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.01 cm |
168,647 |
4.56E-06 |
7,219.41 |
2.37 |
| 100 gm / 3.25 cm |
16,865 |
4.56E-07 |
721.94 |
0.24 |
| 10 gm / 1.51 cm |
1,686 |
4.56E-08 |
72.19 |
0.02 |
| 1 gm / 7.01 mm |
169 |
4.56E-09 |
7.22 |
0.00 |
| 0.1 gm / 3.25 mm |
17 |
4.56E-10 |
0.72 |
0.00 |
| 0.01 gm / 1.51 mm |
2 |
4.56E-11 |
0.07 |
0.00 |
| 0.001 gm / 0.70 mm |
0 |
4.56E-12 |
0.01 |
0.00 |
Weight of pure Vigezzite in grams (gm) and Calculated Diameter of a Sphere with a Density of 5.54 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 0.38 % Th) From Sum REE Elements ( 7.53 % REE)
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Vigezzite Classification
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Dana Class: |
8.3.7.1 (8)Multiple Oxides with Nb, Ta, and Ti |
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(8.3)where A (B2O6) |
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(8.3.7)Dana Group |
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8.3.7.1 Vigezzite (Ca,Ce)(Nb,Ta,Ti)2O6 Pmnb 2/m 2/m 2/m |
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8.3.7.2 Rynersonite Ca(Ta,Nb)2O6 Pmnb 2/m 2/m 2/m |
Strunz Class: |
IV/D.21-40 IV - Oxides |
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IV/D - Oxides with metal : oxygen = 1:2 (MO2 and related compounds) |
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IV/D.21 - Aeschynite series |
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IV/D.21-10 Aeschynite-(Y) (Y,Ca,Fe)(Ti,Nb)2(O,OH)6 Pbnm 2/m 2/m 2/m |
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IV/D.21-20 Aeschynite-(Ce) (Ce,Ca,Fe)(Ti,Nb)2(O,OH)6 Pmnb 2/m 2/m 2/m |
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IV/D.21-30 Aeschynite-(Nd) (Nd,Ce)(Ti,Nb)2(O,OH)6 Pmnb ? 2/m 2/m 2/m |
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IV/D.21-40 Vigezzite (Ca,Ce)(Nb,Ta,Ti)2O6 Pmnb 2/m 2/m 2/m |
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IV/D.21-50 Niobo-aeschynite-(Ce) (Ce,Ca)(Nb,Ti)2(O,OH)6 Pbnm 2/m 2/m 2/m |
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IV/D.21-60 Niobo-aeschynite-(Nd)! (Nd,Ce)(Nb,Ti)2(O,OH)6 Pbnm 2/m 2/m 2/m |
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IV/D.21-70 Rynersonite Ca(Ta,Nb)2O6 Pmnb 2/m 2/m 2/m |
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IV/D.21-80 Tantalaeschynite-(Y) (Y,Ce,Ca)(Ta,Ti,Nb)2O6 Pbnm 2/m 2/m 2/m |
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Other Vigezzite Information
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References: |
NAME( AntBidBlaNic3) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Vigezzite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
13 -École des Mines de Paris
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Vigezzite
(Ca,Ce)(Nb,Ta,Ti)2O6
Dana No: 8.3.7.1 Strunz No: IV/D.21-40
Locality:
Notes:
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