General Tennantite Information
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Chemical Formula: |
(Cu,Fe)12As4S13 |
Composition: |
Molecular Weight = 1,471.40 gm |
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Iron 3.80 % Fe |
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Copper 47.51 % Cu |
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Arsenic 20.37 % As |
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Sulfur 28.33 % S |
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______ |
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100.00 % |
Empirical Formula: |
Cu11Fe2+As4S13 |
Environment: |
Hydrothermal veins and contact metamorphic deposits. |
IMA Status: |
Valid Species (Pre-IMA) 1819 |
Locality: |
Cornwall, England, UK. Link to MinDat.org Location Data. |
Name Origin: |
Named after the English chemist, Smithson Tennant (1761-1815). |
Synonym: |
Binnite |
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ICSD 26780 |
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Julianite |
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PDF 43-1478 |
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Tennantite Image |
Images:
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Tennantite Calcio-andyrobertsite-1M
Comments: Vein of blue calcioandyrobertsite in massive dark gray tennantite. The vein of calcioandyrobertsite extends for 0.8cm.
Location: Tsumeb Mine, Tsumeb, Namibia.
Scale: Specimen size 1.1 x 0.5 cm.
© John Veevaert |
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Images:
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Tennantite
Comments: Crystals of dark gray tennantite on white quartz.
Location: Concepcion del Oro, Zacatecas, Mexico.
Scale: 6 x 5.5 cm.
© Fabre Minerals |
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Images:
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Images:
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Tennantite
Comments: Micro-quartz coated, dark gray tennantite on quartz. Former Sussman Tsumeb specimen.
Location: Tsumeb, Namibia.
Scale: Crystal size 5 cm.
© John Schneider |
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Tennantite Crystallography
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Cell Dimensions: |
a = 10.186, Z = 2; V = 1,056.84 Den(Calc)= 4.62 |
Crystal System: |
Isometric - HextetrahedralH-M Symbol (4 3m) Space Group: I 43m |
X Ray Diffraction: |
By Intensity(I/Io): 2.94(1), 1.801(0.8), 1.535(0.5), |
Forms:
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Forms:
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Crystal Structure:
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Makovicky E , Karanovic L , Poleti D , Balic-Zunic T , Paar W H , The Canadian Mineralogist , 43 (2005) p.679-688, Crystal structure of copper-rich unsubstituted tennantite, Cu12.5As4S13, Sample: Cerro Atajo, Catamarco, Argentina
View Additional jPOWD Structure files for Tennantite
[1]
[2]
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Physical Properties of Tennantite
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Cleavage: |
None |
Color: |
Steel gray, Black. |
Density: |
4.6 - 4.7, Average = 4.65 |
Diaphaniety: |
Opaque |
Fracture: |
Hackly - Jagged, torn surfaces, (e.g. fractured metals). |
Habit: |
Disseminated - Occurs in small, distinct particles dispersed in matrix. |
Habit: |
Massive - Granular - Common texture observed in granite and other igneous rock. |
Habit: |
Massive - Uniformly indistinguishable crystals forming large masses. |
Hardness: |
3.5-4 - Copper Penny-Fluorite |
Luminescence: |
None. |
Luster: |
Metallic |
Magnetism: |
Nonmagnetic |
Streak: |
reddish gray |
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Optical Properties of Tennantite
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Optical Data: |
Isotropic, n=2.72. |
RL Color: |
Gray, inclining to black to brown to cherry-red. |
RL Pleochroism: |
None. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Tennantite in Air
| λ |
R |
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∑ R(λ) |
| 400 nm |
31.40 |
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| 420 nm |
30.60 |
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| 440 nm |
29.80 |
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| 460 nm |
29.20 |
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| 480 nm |
29.00 |
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| 500 nm |
29.00 |
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| 520 nm |
28.80 |
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| 540 nm |
28.50 |
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| 560 nm |
28.00 |
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| 580 nm |
27.30 |
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| 600 nm |
26.40 |
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| 620 nm |
25.60 |
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| 640 nm |
24.80 |
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| 660 nm |
24.20 |
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| 680 nm |
23.80 |
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| 700 nm |
23.40 |
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Calculated Relative Intensity Colors of Tennantite in Air
Relative Intensity |
0% |
40% |
80% |
100% |
120% |
160% |
200% |
240% |
280% |
320% |
340% |
| R |
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Calculated Properties of Tennantite
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Electron Density: |
relectron=4.30 gm/cc note: rTennantite =4.62 gm/cc. |
Fermion Index |
Fermion Index = 0.00292 Boson Index = 0.99708 |
Photoelectric: |
PETennantite = 38.34 barns/electron U=PETennantite x relectron= 164.92 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Tennantite is Not Radioactive |
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Tennantite Classification
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Dana Class: |
3.3.6.2 (3)Sulfides - Sulfosalts |
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(3.3)where 3 < z/y < 4 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.3.6)Tetrahedrite Group (Isometric: I4¯3m) |
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3.3.6.1 Tetrahedrite (Cu,Fe)12Sb4S13 I 43m 4 3m |
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3.3.6.2 Tennantite (Cu,Fe)12As4S13 I 43m 4 3m |
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3.3.6.3 Freibergite (Ag,Cu,Fe)12(Sb,As)4S13 I 43m 4 3m |
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3.3.6.4 Hakite (Cu,Hg)3(Sb,As)(Se,S)3 I 43m 4 3m |
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3.3.6.5 Giraudite (Cu,Zn,Ag)12(As,Sb)4(Se,S)13 I 43m 4 3m |
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3.3.6.6 Goldfieldite Cu12(Te,Sb,As)4S13 I 43m 4 3m |
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3.3.6.7 Argentotennantite (Ag,Cu)10(Zn,Fe)2(As,Sb)4S13 I 43m 4 3m |
Strunz Class: |
II/C.11-10 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.11 - Tetrahedrite group |
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II/C.11-10 Tennantite (Cu,Fe)12As4S13 I 43m 4 3m |
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II/C.11-20 Argentotennantite (Ag,Cu)10(Zn,Fe)2(As,Sb)4S13 I 43m 4 3m |
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II/C.11-30 Giraudite (Cu,Zn,Ag)12(As,Sb)4(Se,S)13 I 43m 4 3m |
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II/C.11-40 Tetrahedrite (Cu,Fe)12Sb4S13 I 43m 4 3m |
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II/C.11-50 Freibergite (Ag,Cu,Fe)12(Sb,As)4S13 I 43m 4 3m |
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II/C.11-60 Goldfieldite Cu12(Te,Sb,As)4S13 I 43m 4 3m |
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II/C.11-70 Hakite (Cu,Hg)3(Sb,As)(Se,S)3 I 43m 4 3m |
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II/C.11-75 Mgriite Cu3AsSe3 F d3m 4/m 3 2/m |
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II/C.11-80 Chameanite (Cu,Fe)4As(Se,S)4 I 43m 4 3m |
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Other Tennantite Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Tennantite :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 - Amethyst Galleries' Mineral Gallery
5 - Applied Mineralogy
6 -Athena
7 - Crocoite.com Mineral Locations
8 - EUROmin Project
9 - Franklin Minerals(Dunn)
10 - Franklin Minerals(Palache)
11 -Google Images
12 -Google Scholar
13 -Handbook of Mineralogy (UofA)
14 - HyperPhysics
15 -MinDAT
16 -MinMax(Deutsch)
17 -MinMax(English)
18 -Mineralienatlas (Deutsch)
19 -QUT Mineral Atlas
20 - Scandinavian mineral gallery
21 - WWW-MINCRYST
22 -École des Mines de Paris
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Print or Cut-and-Paste your Tennantite Specimen Label here :
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Tennantite
(Cu,Fe)12As4S13
Dana No: 3.3.6.2 Strunz No: II/C.11-10
Locality:
Notes:
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