General Giraudite Information
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Chemical Formula: |
(Cu,Zn,Ag)12(As,Sb)4(Se,S)13 |
Composition: |
Molecular Weight = 2,042.97 gm |
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Zinc 11.52 % Zn |
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Copper 22.40 % Cu |
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Silver 6.34 % Ag |
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Antimony 5.96 % Sb |
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Arsenic 11.00 % As |
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Selenium 37.68 % Se |
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Sulfur 5.10 % S |
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______ |
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100.00 % |
Empirical Formula: |
Cu7.2Zn3.6Ag1.2As3SbSe9.75S3.25 |
Environment: |
As late stage deposits in veins cutting granite. |
IMA Status: |
Approved IMA 1982 |
Locality: |
From Chameane, Puy-de-Dome, France. Link to MinDat.org Location Data. |
Name Origin: |
To honor Roger Giraud, of the electron microprobe laboratory of the B.R.G.M.-C.N.R.S. in Orleans, France. |
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Search for Giraudite Images |
Images:
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Giraudite Crystallography
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Cell Dimensions: |
a = 10.578, Z = 2; V = 1,183.62 Den(Calc)= 5.73 |
Crystal System: |
Isometric - HextetrahedralH-M Symbol (4 3m) Space Group: I 43m |
X Ray Diffraction: |
By Intensity(I/Io): 3.05(1), 1.868(0.9), 1.593(0.7), |
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Physical Properties of Giraudite
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Cleavage: |
None |
Color: |
Gray, Steel gray. |
Density: |
5.75 |
Diaphaniety: |
Opaque |
Hardness: |
3.5-4 - Copper Penny-Fluorite |
Luster: |
Metallic |
Streak: |
white |
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Optical Properties of Giraudite
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RL Color: |
Light gray with a creamy tint. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Giraudite in Air
| λ |
R |
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∑ R(λ) |
| 420 nm |
32.20 |
 |
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| 440 nm |
32.10 |
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| 460 nm |
31.80 |
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| 480 nm |
31.70 |
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| 500 nm |
31.60 |
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| 520 nm |
31.50 |
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| 540 nm |
31.70 |
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| 560 nm |
31.80 |
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| 580 nm |
31.70 |
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| 600 nm |
31.70 |
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| 620 nm |
31.80 |
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| 640 nm |
31.60 |
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| 660 nm |
31.50 |
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| 680 nm |
31.30 |
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| 700 nm |
30.80 |
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Calculated Relative Intensity Colors of Giraudite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
240% |
270% |
280% |
| R |
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Calculated Properties of Giraudite
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Electron Density: |
relectron=5.09 gm/cc note: rGiraudite =5.73 gm/cc. |
Fermion Index |
Fermion Index = 0.03374 Boson Index = 0.96626 |
Photoelectric: |
PEGiraudite = 90.89 barns/electron U=PEGiraudite x relectron= 462.28 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Giraudite is Not Radioactive |
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Giraudite Classification
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Dana Class: |
3.3.6.5 (3)Sulfides - Sulfosalts |
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(3.3)where 3 < z/y < 4 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.3.6)Tetrahedrite Group (Isometric: I4¯3m) |
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3.3.6.1 Tetrahedrite (Cu,Fe)12Sb4S13 I 43m 4 3m |
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3.3.6.2 Tennantite (Cu,Fe)12As4S13 I 43m 4 3m |
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3.3.6.3 Freibergite (Ag,Cu,Fe)12(Sb,As)4S13 I 43m 4 3m |
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3.3.6.4 Hakite (Cu,Hg)3(Sb,As)(Se,S)3 I 43m 4 3m |
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3.3.6.5 Giraudite (Cu,Zn,Ag)12(As,Sb)4(Se,S)13 I 43m 4 3m |
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3.3.6.6 Goldfieldite Cu12(Te,Sb,As)4S13 I 43m 4 3m |
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3.3.6.7 Argentotennantite (Ag,Cu)10(Zn,Fe)2(As,Sb)4S13 I 43m 4 3m |
Strunz Class: |
II/C.11-30 II - Sulfides and sulphosalts |
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II/C - Sulfides with metal: sulfur, selenium and tellurium = 1:1 |
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II/C.11 - Tetrahedrite group |
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II/C.11-10 Tennantite (Cu,Fe)12As4S13 I 43m 4 3m |
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II/C.11-20 Argentotennantite (Ag,Cu)10(Zn,Fe)2(As,Sb)4S13 I 43m 4 3m |
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II/C.11-30 Giraudite (Cu,Zn,Ag)12(As,Sb)4(Se,S)13 I 43m 4 3m |
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II/C.11-40 Tetrahedrite (Cu,Fe)12Sb4S13 I 43m 4 3m |
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II/C.11-50 Freibergite (Ag,Cu,Fe)12(Sb,As)4S13 I 43m 4 3m |
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II/C.11-60 Goldfieldite Cu12(Te,Sb,As)4S13 I 43m 4 3m |
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II/C.11-70 Hakite (Cu,Hg)3(Sb,As)(Se,S)3 I 43m 4 3m |
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II/C.11-75 Mgriite Cu3AsSe3 F d3m 4/m 3 2/m |
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II/C.11-80 Chameanite (Cu,Fe)4As(Se,S)4 I 43m 4 3m |
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Other Giraudite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Giraudite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 -École des Mines de Paris
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Print or Cut-and-Paste your Giraudite Specimen Label here :
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Giraudite
(Cu,Zn,Ag)12(As,Sb)4(Se,S)13
Dana No: 3.3.6.5 Strunz No: II/C.11-30
Locality:
Notes:
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