General Pyrolusite Information
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Chemical Formula: |
MnO2 |
Composition: |
Molecular Weight = 86.94 gm |
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Manganese 63.19 % Mn 100.00 % MnO2 |
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Oxygen 36.81 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Mn4+O2 |
Environment: |
Sedimentary, hydrothermal, and secondary. |
IMA Status: |
Valid Species (Pre-IMA) 1827 |
Locality: |
Common world wide. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek, pyro and louein, "fire" and "to wash," because it was used to remove the greenish color imparted to glass by iron compounds. |
Synonym: |
ICSD 73716 |
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PDF 24-735 |
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Polianite |
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Wad |
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Pyrolusite Image |
Images:
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Pyrolusite Crystallography
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Axial Ratios: |
a:c = 1:0.65148 |
Cell Dimensions: |
a = 4.39, c = 2.86, Z = 2; V = 55.12 Den(Calc)= 5.24 |
Crystal System: |
Tetragonal - Ditetragonal DipyramidalH-M Symbol (4/m 2/m 2/m) Space Group: P 4/mnm |
X Ray Diffraction: |
By Intensity(I/Io): 3.14(1), 1.63(0.5), 2.41(0.5), |
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Crystal Structure:
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Wyckoff R W G , Crystal Structures , 1 (1963) p.239-444, Second edition. Interscience Publishers, New York, New York, Note: beta phase of MnO2, rutile structure
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Physical Properties of Pyrolusite
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Cleavage: |
[110] Perfect |
Color: |
Steel gray, Iron gray, Bluish gray. |
Density: |
4.4 - 5.06, Average = 4.73 |
Diaphaniety: |
Opaque |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Habit: |
Dendritic - Branching "tree-like" growths of great complexity (e.g. pyrolusite). |
Habit: |
Earthy - Dull, clay-like texture with no visible crystalline affinities, (e.g. howlite). |
Habit: |
Reniform - "Kidney like" in shape (e.g.. hematite). |
Hardness: |
6-6.5 - Orthoclase-Pyrite |
Luminescence: |
None. |
Luster: |
Sub Metallic |
Magnetism: |
Nonmagnetic |
Streak: |
black |
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Optical Properties of Pyrolusite
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Optical Data: |
Uniaxial (?). |
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NCalc= 3.06 - from Gladstone-Dale relationship (KC = 0.394) where Ncalc=Dcalc*KC+1
NCalc= 2.86 - from Gladstone-Dale relationship (KC = 0.394) where Ncalc=Dmeas*KC+1 |
RL Anisotrophism: |
Strong in yellow. |
RL Bireflectance: |
Weak, yellow to yellow-gray. |
RL Color: |
White with creamy yellow tint. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Pyrolusite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
18.40 |
29.40 |

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| 420 nm |
18.60 |
30.00 |

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| 440 nm |
18.80 |
30.60 |

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| 460 nm |
18.90 |
31.20 |

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| 480 nm |
19.00 |
31.60 |

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| 500 nm |
19.00 |
31.70 |

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| 520 nm |
18.90 |
31.60 |

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| 540 nm |
18.80 |
31.40 |

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| 560 nm |
18.60 |
31.20 |

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| 580 nm |
18.50 |
30.80 |

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| 600 nm |
18.40 |
30.40 |

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| 620 nm |
18.30 |
30.00 |

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| 640 nm |
18.20 |
29.50 |

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| 660 nm |
18.20 |
28.90 |

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| 680 nm |
18.10 |
28.40 |

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| 700 nm |
18.10 |
28.00 |

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Calculated Relative Intensity Colors of Pyrolusite in Air
Relative Intensity |
0% |
50% |
100% |
150% |
200% |
250% |
300% |
350% |
400% |
450% |
480% |
| R1 |
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| R2 |
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Calculated Properties of Pyrolusite
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Electron Density: |
relectron=4.94 gm/cc note: rPyrolusite =5.24 gm/cc. |
Fermion Index |
Fermion Index = 0.00017 Boson Index = 0.99983 |
Photoelectric: |
PEPyrolusite = 16.61 barns/electron U=PEPyrolusite x relectron= 82.07 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Pyrolusite is Not Radioactive |
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Pyrolusite Classification
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Dana Class: |
4.4.1.4 (4)Simple Oxides |
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(4.4)with a cation charge of 4+ (A++++ O2) |
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(4.4.1)Rutile group (Tetragonal: P4/mnm) |
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4.4.1.1 Rutile TiO2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.2 Ilmenorutile (Ti,Nb,Fe)O2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.3 Struverite (Ti,Ta,Fe)O2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.4 Pyrolusite MnO2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.5 Cassiterite SnO2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.6 Plattnerite PbO2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.7 Argutite GeO2 P 4/mnm 4/m 2/m 2/m |
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4.4.1.8 Squawcreekite? (Fe,Sb,W)O4·(H2O) P 4/mnm 4/m 2/m 2/m |
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4.4.1.9 Stishovite SiO2 P 4/mnm 4/m 2/m 2/m |
Strunz Class: |
IV/D.02-20 IV - Oxides |
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IV/D - Oxides with metal : oxygen = 1:2 (MO2 and related compounds) |
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IV/D.02 - Rutile group, Rutile - Cassiterite - Platnerite series |
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IV/D.02-10 Rutile TiO2 P 4/mnm 4/m 2/m 2/m |
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IV/D.02-20 Pyrolusite MnO2 P 4/mnm 4/m 2/m 2/m |
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IV/D.02-30 Squawcreekite? (Fe,Sb,W)O4·(H2O) P 4/mnm 4/m 2/m 2/m |
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IV/D.02-40 Cassiterite SnO2 P 4/mnm 4/m 2/m 2/m |
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IV/D.02-45 Argutite GeO2 P 4/mnm 4/m 2/m 2/m |
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IV/D.02-50 Paratellurite TeO2 P 41212,P 43212 4 2 2 |
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IV/D.02-60 Plattnerite PbO2 P 4/mnm 4/m 2/m 2/m |
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Other Pyrolusite Information
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References: |
NAME( Sinkankas66) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Pyrolusite :
1 -Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 - Applied Mineralogy
4 -Athena
5 - Crocoite.com Mineral Locations
6 - EUROmin Project
7 - Glendale Community College
8 -Google Images
9 -Google Scholar
10 -Handbook of Mineralogy (UofA)
11 - HyperPhysics
12 -MinDAT
13 -MinMax(Deutsch)
14 -MinMax(English)
15 -Mineralienatlas (Deutsch)
16 - Minerals of Wisconsin
17 -QUT Mineral Atlas
18 - Scandinavian mineral gallery
19 -University of Colorado - Mineral Structure Data
20 -University of Minnesota
21 - WWW-MINCRYST
22 - YupRocks
23 -École des Mines de Paris
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Print or Cut-and-Paste your Pyrolusite Specimen Label here :
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Pyrolusite
MnO2
Dana No: 4.4.1.4 Strunz No: IV/D.02-20
Locality:
Notes:
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