General Metazeunerite Information
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Chemical Formula: |
Cu(UO2)2(AsO4)2·8(H2O) |
Composition: |
Molecular Weight = 1,025.56 gm |
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Uranium 46.42 % U 52.66 % UO2 |
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Copper 6.20 % Cu 7.76 % CuO |
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Arsenic 14.61 % As 22.41 % As2O5 |
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Hydrogen 1.57 % H 14.05 % H2O |
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Oxygen 31.20 % O |
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______ ______ |
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100.00 % 96.88 % = TOTAL OXIDE |
Empirical Formula: |
Cu(UO2)2(AsO4)2·8(H2O) |
IMA Status: |
Valid Species (Pre-IMA) 1937 |
Locality: |
Weisser Hirsch mine, Schneeberg, Sachsen (Saxony), Germany Link to MinDat.org Location Data. |
Name Origin: |
Named as the lower hydrate of zeunerite |
Synonym: |
ICSD 38122 |
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PDF 17-146 |
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Metazeunerite Image |
Images:
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Images:
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Metazeunerite Crystallography
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Axial Ratios: |
a:c = 1:2.45352 |
Cell Dimensions: |
a = 7.1, c = 17.42, Z = 2; V = 878.14 Den(Calc)= 3.88 |
Crystal System: |
Tetragonal - DipyramidalH-M Symbol (4/m) Space Group: P 4/n |
X Ray Diffraction: |
By Intensity(I/Io): 3.73(1), 8.86(1), 5.57(0.8), |
Crystal Structure:
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Locock A J , Burns P C , The Canadian Mineralogist , 41 (2003) p.489-502, Crystal structures and synthesis of the copper-dominant members of the autunite, and meta-autunite groups: Tobernite, zeunerite, metatorbernite and metazeunerite
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Physical Properties of Metazeunerite
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Cleavage: |
[001] Perfect, [100] Distinct |
Color: |
Green, Grass green, Emerald green. |
Density: |
3.64 |
Diaphaniety: |
Transparent to Translucent |
Hardness: |
2-2.5 - Gypsum-Finger Nail |
Luminescence: |
Fluorescent. |
Luster: |
Vitreous - Pearly |
Streak: |
greenish white |
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Optical Properties of Metazeunerite
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Dichroism (e): |
colorless. |
Dichroism (w): |
colorless. |
Gladstone-Dale: |
CI meas= -0.169 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.097 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1644,KPDmeas= 0.1753,KC= 0.1499 |
Optical Data: |
Uniaxial (-), e=1.626, w=1.65, bire=0.0240. |
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Calculated Properties of Metazeunerite
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Electron Density: |
relectron=3.44 gm/cc note: rMetazeunerite =3.88 gm/cc. |
Fermion Index |
Fermion Index = 0.00349 Boson Index = 0.99651 |
Photoelectric: |
PEMetazeunerite =1,200.52 barns/electron U=PEMetazeunerite x relectron=4,133.15 barns/cc. |
Radioactivity: |
GRapi = 3,510,838.14 (Gamma Ray American Petroleum Institute Units)
Metazeunerite is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 10 cm box)
8.66 ± 2.17 grams of pure Metazeunerite .
Estimated Maximum U.S. Postal Shipping Size
(10 mRem/hr limit, Unshielded 100 cm box)
866.36 ±216.59 grams of pure Metazeunerite .
Estimated Radioactivity from Metazeunerite - very strong
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.90 cm |
83,090,386 |
2.25E-03 |
3,510,838.14 |
1,154.25 |
| 100 gm / 3.66 cm |
8,309,039 |
2.25E-04 |
351,083.81 |
115.42 |
| 10 gm / 1.70 cm |
830,904 |
2.25E-05 |
35,108.38 |
11.54 |
| 1 gm / 7.90 mm |
83,090 |
2.25E-06 |
3,510.84 |
1.15 |
| 0.1 gm / 3.66 mm |
8,309 |
2.25E-07 |
351.08 |
0.12 |
| 0.01 gm / 1.70 mm |
831 |
2.25E-08 |
35.11 |
0.01 |
| 0.001 gm / 0.79 mm |
83 |
2.25E-09 |
3.51 |
0.00 |
Weight of pure Metazeunerite in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.88 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
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Metazeunerite Classification
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Dana Class: |
40.2a.14.2 (40)Hydrated Phosphates, etc |
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(40.2a)where A++ (B++)2 (XO4) · x(H2O), containing (UO2)++ |
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(40.2a.14)Dana Group |
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40.2a.14.1 Zeunerite Cu(UO2)2(AsO4)2·10-16(H2O) P 4/nnc 4/m 2/m 2/m |
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40.2a.14.2 Metazeunerite Cu(UO2)2(AsO4)2·8(H2O) P 4/n 4/m |
Strunz Class: |
VII/E.02-70 VII - Phosphates, Arsenates and Vanadates |
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VII/E - Uranylphosphates and uranylvanadates with [UO2]2+ - [PO4 | AsO4]3- and [UO2]2+ - [V2O8]6- |
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VII/E.02 - Meta-autunite group |
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VII/E.02-10 Metanovacekite Mg(UO2)2(AsO4)2·4-8(H2O) P 4/n 4/m |
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VII/E.02-20 Bassetite Fe(UO2)2(PO4)2·8(H2O) P 21/m 2/m |
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VII/E.02-30 Metakahlerite Fe(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-40 Lehnerite Mn[UO2/PO4]2·8(H2O) P 21/n 2/m |
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VII/E.02-50 Metakirchheimerite Co(UO2)2(AsO4)2·8(H2O) P 4/mmm 4/m 2/m 2/m |
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VII/E.02-60 Metatorbernite Cu(UO2)2(PO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-70 Metazeunerite Cu(UO2)2(AsO4)2·8(H2O) P 4/n 4/m |
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VII/E.02-80 Metalodevite Zn(UO2)2(AsO4)2·10(H2O) P 41/m 4/m |
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VII/E.02-90 Meta-autunite Ca(UO2)2(PO4)2·2-6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-95 Sodium meta-autunite! Na2(UO2)2(PO4)2·6-8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-100 Meta-uranospinite Ca(UO2)2(AsO4)2·8(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-110 Meta-uranocircite Ba(UO2)2(PO4)2·6-8(H2O) P 21 2 |
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VII/E.02-120 Metaheinrichite Ba(UO2)2(AsO4)2·8(H2O) P 41/? 4/m |
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VII/E.02-130 Sodium-uranospinite (Na2,Ca)(UO2)2(AsO4)2·5(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-140 Meta-ankoleite K2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-150 Abernathyite K(UO2)(AsO4)·4(H2O) P 4/ncc 4/m 2/m 2/m |
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VII/E.02-160 Uramphite (NH4)(UO2)(PO4)·3(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-170 Chernikovite (H3O)2(UO2)2(PO4)2·6(H2O) P 4/nmm 4/m 2/m 2/m |
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VII/E.02-180 Pseudo-autunite* (H3O)4Ca2(UO2)2(PO4)4·5(H2O)(?) Unk Ortho |
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VII/E.02-190 Ulrichite CaCu(UO2)(PO4)2·4(H2O) C 2/m 2/m |
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Other Metazeunerite Information
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References: |
PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Metazeunerite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 - Franklin Minerals(Dunn)
6 -Google Images
7 -Google Scholar
8 -Handbook of Mineralogy (UofA)
9 -MinDAT
10 -MinMax(Deutsch)
11 -MinMax(English)
12 -Mineralienatlas (Deutsch)
13 -QUT Mineral Atlas
14 -École des Mines de Paris
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Metazeunerite
Cu(UO2)2(AsO4)2·8(H2O)
Dana No: 40.2a.14.2 Strunz No: VII/E.02-70
Locality:
Notes:
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