General Kukharenkoite-(Ce) Information
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Chemical Formula: |
Ba2Ce(CO3)3F |
Composition: |
Molecular Weight = 613.80 gm |
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Barium 44.75 % Ba 49.96 % BaO |
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Cerium 22.83 % Ce 26.74 % Ce2O3 |
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Carbon 5.87 % C 21.51 % CO2 |
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Oxygen 23.46 % O |
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Fluorine 3.10 % F 3.10 % F |
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- % F -1.30 % -O=F2 |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Ba2Ce(CO3)3F |
Environment: |
Alkaline igneous rocks. |
IMA Status: |
Approved IMA 1996 (Dana # Added) |
Locality: |
Khibina alkaline massif, Kola peninsula, Russia; Vuorijarvi alkaline massif, Kola peninsula, Russia; Mont Saint-Hilare alkaline complex, Rouville County, Quebec, Canada. Link to MinDat.org Location Data.
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Name Origin: |
For Prof. Alexander A. Kukharenko (1914-1993), Department of Mineralogy, St. Petersburg University, St. Petersburg, Russia. |
Synonym: |
ICSD 85572 |
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IMA1995-040 |
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PDF 81-1079 |
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Kukharenkoite-(Ce) Image |
Images:
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Kukharenkoite-(Ce)
Comments: White-tan crystals of kukharenkoite-(Ce).
Location: Kirovskii (Kirovsky) apatite mine, Mt Kukisvumchorr, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia.
Scale: Picture size 4 mm.
© Thomas Witzke / Abraxas-Verlag |
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Kukharenkoite-(Ce) Crystallography
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Axial Ratios: |
a:b:c =2.6431:1:1.3223 |
Cell Dimensions: |
a = 13.406, b = 5.072, c = 6.707, Z = 2; beta = 106.566° V = 437.11 Den(Calc)= 4.66 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/m |
X Ray Diffraction: |
By Intensity(I/Io): 3.269(1), 2.003(0.4), 2.14(0.4), |
Crystal Structure:
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drag2 - RMB Resize/Rotate
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Krivovichev S V , Filatov S K , Zaitsev A N , The Canadian Mineralogist , 36 (1998) p.809-815, The crystal structure of kukharenkoite-(Ce), Ba2REE(CO3)3F,and an interpretation, based on cation-coordinated F tetrahedra
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Physical Properties of Kukharenkoite-(Ce)
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Cleavage: |
None |
Color: |
Yellow, Reddish brown, Colorless, White, Pinkish gray. |
Density: |
4.61 - 4.7, Average = 4.65 |
Diaphaniety: |
Transparent to translucent to opaque |
Fracture: |
Brittle - Uneven - Very brittle fracture producing uneven fragments. |
Habit: |
Dendritic - Branching "tree-like" growths of great complexity (e.g. pyrolusite). |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Habit: |
Stellate - Occurs as spherical, radial aggregates radiating from a "star" like point. |
Hardness: |
4.5 - Between Fluorite and Apatite |
Luster: |
Vitreous - Greasy |
Streak: |
white |
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Optical Properties of Kukharenkoite-(Ce)
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Gladstone-Dale: |
CI meas= 0.028 (Excellent) - where the CI = (1-KPDmeas/KC) CI calc= 0.029 (Excellent) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.145,KPDmeas= 0.1452,KC= 0.1493 |
Optical Data: |
Biaxial (-), a=1.584-1.594, b=1.71-1.724, g=1.715-1.728, bire=0.1310-0.1340, 2V(Calc)=18-20, 2V(Meas)=16. Dispersion r > v moderate. |
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Calculated Properties of Kukharenkoite-(Ce)
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Electron Density: |
relectron=4.08 gm/cc note: rKukharenkoite-(Ce) =4.66 gm/cc. |
Fermion Index |
Fermion Index = 0.0805 Boson Index = 0.9195 |
Photoelectric: |
PEKukharenkoite-(Ce) = 324.96 barns/electron U=PEKukharenkoite-(Ce) x relectron=1,325.88 barns/cc. |
Radioactivity: |
GRapi = 21,342.66 (Gamma Ray American Petroleum Institute Units)
Kukharenkoite-(Ce) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Radioactivity from Kukharenkoite-(Ce) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 7.43 cm |
511,339 |
1.38E-05 |
21,342.66 |
7.02 |
| 100 gm / 3.45 cm |
51,134 |
1.38E-06 |
2,134.27 |
0.70 |
| 10 gm / 1.60 cm |
5,113 |
1.38E-07 |
213.43 |
0.07 |
| 1 gm / 7.43 mm |
511 |
1.38E-08 |
21.34 |
0.01 |
| 0.1 gm / 3.45 mm |
51 |
1.38E-09 |
2.13 |
0.00 |
| 0.01 gm / 1.60 mm |
5 |
1.38E-10 |
0.21 |
0.00 |
| 0.001 gm / 0.74 mm |
1 |
1.38E-11 |
0.02 |
0.00 |
Weight of pure Kukharenkoite-(Ce) in grams (gm) and Calculated Diameter of a Sphere with a Density of 4.66 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
**
Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 1.14 % Th) From Sum REE Elements (22.83 % REE)
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Kukharenkoite-(Ce) Classification
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Dana Class: |
16a.1.8.2 (16a)Carbonates - Hydroxyl or Halogen |
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(16a.1)in the Bastnasite/Shynchysite/Parasite Groups |
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(16a.1.8)Dana Group |
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16a.1.8.1 Zhonghuacerite-(Ce) Ba2Ce(CO3)3F P 21/m 2/m |
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16a.1.8.2 Kukharenkoite-(Ce) ! Ba2Ce(CO3)3F P 21/m 2/m |
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16a.1.8.3 Kukharenkoite-(La)! Ba2(La,Ce)(CO3)3F P 21/m 2/m |
Strunz Class: |
V/C.07-155 V - Nitrates, Carbonates and Borates |
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V/C - Waterfree carbonates with unfamiliar anions |
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V/C.07 - Bastnäsite-(Y) - Mineevite-(Y) series |
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V/C.07-10 Bastnasite-(Y) Y(CO3)F P 62c 6 m2 |
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V/C.07-20 Bastnasite-(La) La(CO3)F P 62c 6 m2 |
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V/C.07-30 Bastnasite-(Ce) Ce(CO3)F P 62c 6 m2 |
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V/C.07-40 Hydroxylbastnasite-(La) La(CO3)(OH) C 2221 2 2 2 |
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V/C.07-50 Hydroxylbastnasite-(Ce) Ce(CO3)(OH) P 62c 6 m2 |
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V/C.07-60 Hydroxylbastnasite-(Nd) Nd(CO3)(OH) P 62c 6 m2 |
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V/C.07-61 Kozoite-(Nd)! (Nd,La,Sm,Pr)(CO3)(OH) Pmcn 2/m 2/m 2/m |
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V/C.07-62 Kozoite-(La)! La(CO3)(OH) Pmcn 2/m 2/m 2/m |
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V/C.07-64 Horvathite-(Y)! NaY(CO3)F2 Pmcn 2/m 2/m 2/m |
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V/C.07-70 Parisite-(Ce) Ca(Ce,La)2(CO3)3F2 R 3 3 |
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V/C.07-80 Parisite-(Nd) Ca(Nd,Ce,La)2(CO3)3F2 R 3 3 |
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V/C.07-90 Rontgenite-(Ce) Ca2(Ce,La)3(CO3)5F3 R 3 3 |
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V/C.07-100 Synchysite-(Y) CaY(CO3)2F C 2/c 2/m |
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V/C.07-110 Synchysite-(Ce) CaCe(CO3)2F C 2/c 2/m |
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V/C.07-120 Synchysite-(Nd) CaNd(CO3)2F Unk Ortho |
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V/C.07-130 Huanghoite-(Ce) BaCe(CO3)2F R 3m 3 2/m |
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V/C.07-140 Cebaite-(Ce) Ba3Ce2(CO3)5F2 C 2/m or C 2 Mono |
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V/C.07-150 Cebaite-(Nd)! Ba3(Nd,Ce)2(CO3)5F2 Unk Mono |
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V/C.07-154 Kukharenkoite-(La)! Ba2(La,Ce)(CO3)3F P 21/m 2/m |
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V/C.07-155 Kukharenkoite-(Ce) Ba2Ce(CO3)3F P 21/m 2/m |
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V/C.07-160 Zhonghuacerite-(Ce) Ba2Ce(CO3)3F P 21/m 2/m |
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V/C.07-170 Cordylite-(Ce) Ba(Ce,La)2(CO3)3F2 P 63/mmc 6/m 2/m 2/m |
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V/C.07-175 Lukechangite-(Ce)! Na3Ce2(CO3)4F P 63/mmc 6/m 2/m 2/m |
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V/C.07-190 Mineevite-(Y) Na25Ba(Y,Gd,Dy)2(HCO3)4(CO3)11(SO4)2ClF2 P 63/m 6/m |
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V/C.07-200 Reederite-(Y)! Na15Y2(CO3)9(SO3F)Cl P 6 6 |
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V/C.07-210 Micheelsenite! (Ca,Y)3Al[PO3OH,CO3](CO3)(OH)6·12(H2O) P 63 6 |
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Other Kukharenkoite-(Ce) Information
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References: |
NAME( MinRec) PHYS. PROP.(Eur. J. Min.,Vol.8,1996) OPTIC PROP.(MinRec) |
See Also: |
Links to other databases for Kukharenkoite-(Ce) :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 -Athena
5 -Google Images
6 -Google Scholar
7 -Handbook of Mineralogy (UofA)
8 -MinDAT
9 -MinMax(Deutsch)
10 -MinMax(English)
11 -Mineralienatlas (Deutsch)
12 -QUT Mineral Atlas
13 - WWW-MINCRYST
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Print or Cut-and-Paste your Kukharenkoite-(Ce) Specimen Label here :
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Kukharenkoite-(Ce)
Ba2Ce(CO3)3F
Dana No: 16a.1.8.2 Strunz No: V/C.07-155
Locality:
Notes:
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