General Jarosite Information
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Chemical Formula: |
KFe+++3(SO4)2(OH)6 |
Composition: |
Molecular Weight = 500.81 gm |
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Potassium 7.81 % K 9.40 % K2O |
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Iron 33.45 % Fe 47.83 % Fe2O3 |
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Hydrogen 1.21 % H 10.79 % H2O |
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Sulfur 12.81 % S 31.97 % SO3 |
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Oxygen 44.73 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
KFe3+3(SO4)2(OH)6 |
Environment: |
Secondary mineral, forming under conditions of weathering in arid climates. |
IMA Status: |
Valid Species (Pre-IMA) 1852 |
Locality: |
Barranco Jaroso in southern Spain. Link to MinDat.org Location Data. |
Name Origin: |
Named after its locality. |
Synonym: |
ICSD 12107 |
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PDF 36-427 |
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Utahite |
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Jarosite Image |
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Jarosite
Comments: Deep brown lustrous crystals of Jarosite to 2 mm.
Location: Soureza, Attika, Greece.
Scale: 2.8 x 1.6 cm.
© John Veevaert |
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Images:
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Jarosite Crystallography
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Axial Ratios: |
a:c = 1:2.36199 |
Cell Dimensions: |
a = 7.21, c = 17.03, Z = 3; V = 766.68 Den(Calc)= 3.25 |
Crystal System: |
Trigonal - PyramidalH-M Symbol (3) Space Group: R 3 |
X Ray Diffraction: |
By Intensity(I/Io): 3.08(1), 3.11(0.6), 2.292(0.5), |
Forms:
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Crystal Structure:
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Becker U , Gasharova B , Physics and Chemistry of Minerals , 28 (2001) p.545-556, AFM observations and simulations of jarosite growth at the molecular scale:, probing the basis for the incorporation of foreign ions into jarosite, as a storage mineral
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Physical Properties of Jarosite
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Cleavage: |
[0001] Distinct |
Color: |
Brown, Yellow, Yellow brown, Light yellow. |
Density: |
2.9 - 3.3, Average = 3.09 |
Diaphaniety: |
Translucent |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Crystalline - Fine - Occurs as well-formed fine sized crystals. |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Massive - Uniformly indistinguishable crystals forming large masses. |
Hardness: |
2.5-3.5 - Finger Nail-Copper Penny |
Luminescence: |
None. |
Luster: |
Vitreous (Glassy) |
Streak: |
yellow |
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Optical Properties of Jarosite
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Dichroism (e): |
colorless, very pale yellow, or pale greenish yellow. |
Dichroism (w): |
colorless, deep golden yellow, or deep golden yellow. |
Gladstone-Dale: |
CI meas= 0.059 (Good) - where the CI = (1-KPDmeas/KC) CI calc= 0.102 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2356,KPDmeas= 0.247,KC= 0.2624 |
Optical Data: |
Uniaxial (-), e=1.713-1.715, w=1.815-1.82, bire=0.1020-0.1050. |
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Calculated Properties of Jarosite
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Electron Density: |
relectron=3.06 gm/cc note: rJarosite =3.10 gm/cc. |
Fermion Index |
Fermion Index = 0.00827 Boson Index = 0.99173 |
Photoelectric: |
PEJarosite = 11.47 barns/electron U=PEJarosite x relectron= 35.09 barns/cc. |
Radioactivity: |
GRapi = 111.13 (Gamma Ray American Petroleum Institute Units)
Estimated Radioactivity from Jarosite - barely detectable
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Jarosite Classification
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Dana Class: |
30.2.5.1 (30)Anhydrous Sulfates Containing Hydroxyl or Halogen |
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(30.2)where (A B)2 XO4 Zq |
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(30.2.5)Alunite Group (Jarosite Subgroup) |
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30.2.5.1 Jarosite KFe3(SO4)2(OH)6 R 3 3 |
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30.2.5.2 Natrojarosite NaFe3(SO4)2(OH)6 R 3m 3m |
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30.2.5.3 Hydronium-jarosite (H3O)Fe3(SO4)2(OH)6 R 3m 3m |
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30.2.5.4 Ammoniojarosite (NH4)Fe3(SO4)2(OH)6 R 3m 3m |
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30.2.5.5 Argentojarosite AgFe3(SO4)2(OH)6 R 3m 3m |
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30.2.5.6 Plumbojarosite PbFe6(SO4)4(OH)12 R 3m 3 2/m |
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30.2.5.7 Beaverite PbCu(Fe,Al)2(SO4)2(OH)6 R 3m 3m |
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30.2.5.8 Dorallcharite (Tl,K)Fe3(SO4)2(OH)6 R 3m 3 2/m |
Strunz Class: |
VI/B.11-60 VI - Sulfates,Chromates,Molybdates and Tungstates |
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VI/B - Waterfree sulfates [SO4]2- with unfamiliar anions. mostly big cations |
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VI/B.11 - Alunite group, Natroalunite - Jarosite - Beaverite |
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VI/B.11-10 Natroalunite NaAl3(SO4)2(OH)6 R 3m 3 2/m |
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VI/B.11-20 Alunite KAl3(SO4)2(OH)6 R 3m, R 3m Trig |
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VI/B.11-30 Ammonioalunite (NH4)Al3(SO4)2(OH)6 R 3m 3 2/m |
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VI/B.11-40 Minamiite (Na,Ca,K)Al3(SO4)2(OH)6 R 3m 3 2/m |
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VI/B.11-43 Huangite Ca0.5Al3(SO4)2(OH)6 R 3m 3 2/m |
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VI/B.11-45 Walthierite Ba0.5Al3(SO4)2(OH)6 R 3m 3 2/m |
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VI/B.11-50 Natrojarosite NaFe3(SO4)2(OH)6 R 3m 3m |
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VI/B.11-60 Jarosite KFe3(SO4)2(OH)6 R 3 3 |
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VI/B.11-65 Dorallcharite (Tl,K)Fe3(SO4)2(OH)6 R 3m 3 2/m |
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VI/B.11-70 Ammoniojarosite (NH4)Fe3(SO4)2(OH)6 R 3m 3m |
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VI/B.11-80 Hydronium-jarosite (H3O)Fe3(SO4)2(OH)6 R 3m 3m |
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VI/B.11-90 Argentojarosite AgFe3(SO4)2(OH)6 R 3m 3m |
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VI/B.11-100 Plumbojarosite PbFe6(SO4)4(OH)12 R 3m 3 2/m |
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VI/B.11-110 Osarizawaite PbCuAl2(SO4)2(OH)6 R 3m 3m |
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VI/B.11-120 Beaverite PbCu(Fe,Al)2(SO4)2(OH)6 R 3m 3m |
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Other Jarosite Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Heinrich65) |
See Also: |
Links to other databases for Jarosite :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 - Amethyst Galleries' Mineral Gallery
5 -Athena
6 - CalTech Mineral Spectroscopy
7 - Crocoite.com Mineral Locations
8 - EUROmin Project
9 -Google Images
10 -Google Scholar
11 -Handbook of Mineralogy (UofA)
12 -MinDAT
13 -MinMax(Deutsch)
14 -MinMax(English)
15 - Mineral and Gemstone Kingdom
16 -Mineralienatlas (Deutsch)
17 - Minerals of Wisconsin
18 -QUT Mineral Atlas
19 - WWW-MINCRYST
20 -École des Mines de Paris
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Print or Cut-and-Paste your Jarosite Specimen Label here :
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Jarosite
KFe+++3(SO4)2(OH)6
Dana No: 30.2.5.1 Strunz No: VI/B.11-60
Locality:
Notes:
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