General Hellandite-(Y) Information
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Chemical Formula: |
(Ca,REE)4(Y,Ce)2(Al,[ ])2[Si4B4O22](OH)2 |
Composition: |
Molecular Weight = 1,029.47 gm |
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Calcium 11.68 % Ca 16.34 % CaO |
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Cerium 6.81 % Ce 7.97 % Ce2O3 |
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La,Ce,Pr,Nd,Sm, 13.99 % RE 16.32 % REE2O3 |
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Yttrium 12.95 % Y 16.45 % Y2O3 |
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Aluminum 1.97 % Al 3.71 % Al2O3 |
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Silicon 10.91 % Si 23.35 % SiO2 |
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Boron 4.20 % B 13.53 % B2O3 |
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Hydrogen 0.20 % H 1.75 % H2O |
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Oxygen 37.30 % O |
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______ ______ |
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100.00 % 99.42 % = TOTAL OXIDE |
Empirical Formula: |
Ca3REEY1.5Ce0.5Al0.75(Si4B4O22)(OH)2 |
Environment: |
Pegmatite |
IMA Status: |
Valid Species (Pre-IMA) 1903 |
Locality: |
Kragero, Telemark, Norway. Link to MinDat.org Location Data. |
Name Origin: |
Named for Amund Theodor Helland (1846-1918), geologist of Oslo, Norway. |
Synonym: |
Hellandite |
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ICSD 100145 |
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IMA2000-F |
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PDF 25-184 |
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Search for Hellandite-(Y) Images |
Images:
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Hellandite-(Y) Crystallography
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Axial Ratios: |
a:b:c =4.0275:1:2.1845 |
Cell Dimensions: |
a = 18.99, b = 4.715, c = 10.3, Z = 2; beta = 111.4° V = 858.66 Den(Calc)= 3.98 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 2/a |
X Ray Diffraction: |
By Intensity(I/Io): 2.63(1), 1.89(0.6), 2.82(0.6), |
Crystal Structure:
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Mellini M , Merlino S , American Mineralogist , 62 (1977) p.89-99, Hellandite: a new type of silicoborate chain
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Physical Properties of Hellandite-(Y)
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Cleavage: |
[001] Poor, [100] Poor |
Color: |
Green yellow, Grayish black, Reddish brown, Black. |
Density: |
3.7 |
Diaphaniety: |
Translucent to subtranslucent |
Fracture: |
Brittle - Conchoidal - Very brittle fracture producing small, conchoidal fragments. |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Hardness: |
5.5-6 - Knife Blade-Orthoclase |
Luminescence: |
Non-fluorescent. |
Luster: |
Vitreous - Greasy |
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Optical Properties of Hellandite-(Y)
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Gladstone-Dale: |
CI meas= 0.057 (Good) - where the CI = (1-KPDmeas/KC) CI calc= 0.123 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.1633,KPDmeas= 0.1757,KC= 0.1863 |
Optical Data: |
Biaxial (+), a=1.64, b=1.65, g=1.66, bire=0.0200, 2V(Calc)=88, 2V(Meas)=80. |
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Calculated Properties of Hellandite-(Y)
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Electron Density: |
relectron=3.51 gm/cc note: rHellandite-(Y) =3.70 gm/cc. |
Fermion Index |
Fermion Index = 0.03981 Boson Index = 0.96019 |
Photoelectric: |
PEHellandite-(Y) = 134.74 barns/electron U=PEHellandite-(Y) x relectron= 472.90 barns/cc. |
Radioactivity: |
GRapi = 21,088.75 (Gamma Ray American Petroleum Institute Units)
Hellandite-(Y) is Radioactive as defined in 49 CFR 173.403. Greater than 70 Bq / gram.
Estimated Radioactivity from Hellandite-(Y) - weak
Specimen Size Weight/Volume (Sphere) * |
Calculated Activity Bequerols (Bq) |
Calculated Activity Curies (Ci) |
Estimated Activity GR(api) |
Estimated Exposure (mRem**)/hr If Held in Hand For One Hour |
| 1000 gm / 8.02 cm |
466,887 |
1.26E-05 |
21,088.75 |
6.93 |
| 100 gm / 3.72 cm |
46,689 |
1.26E-06 |
2,108.88 |
0.69 |
| 10 gm / 1.73 cm |
4,669 |
1.26E-07 |
210.89 |
0.07 |
| 1 gm / 8.02 mm |
467 |
1.26E-08 |
21.09 |
0.01 |
| 0.1 gm / 3.72 mm |
47 |
1.26E-09 |
2.11 |
0.00 |
| 0.01 gm / 1.73 mm |
5 |
1.26E-10 |
0.21 |
0.00 |
| 0.001 gm / 0.80 mm |
0 |
1.26E-11 |
0.02 |
0.00 |
Weight of pure Hellandite-(Y) in grams (gm) and Calculated Diameter of a Sphere with a Density of 3.70 gm/cc.*
Goverment Estimate of Average Annual Exposure (
360 mRem)
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Note: 10 microsieverts/hr = 1 mRem/hr **
Max Permissable Adult Dose 50,000 mRem/yr (hands), 15,000 mRem/yr (eyes)
Lethal Dose LD(50) Exposure 400,000 to 500,000 mRem
Estimated Thorium Activity ( 1.04 % Th) From Sum REE Elements (20.79 % REE)
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Hellandite-(Y) Classification
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Dana Class: |
54.2.2.1 (54)Nesosilicate Borosilicates and Some Beryllosilicates |
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(54.2)with B in [4] coordination |
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(54.2.2)Hellandite group |
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54.2.2.1 Hellandite-(Y) (Ca,REE)4(Y,Ce)2(Al,[])2[Si4B4O22](OH)2 P 2/a 2/m |
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54.2.2.2 Tadzhikite-(Y)! Ca4(Y,Ce)2(Ti,Al,Fe,[])2[Si4B4O22](OH)2 P 2/a 2/m |
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54.2.2.3 Tadzhikite-(Ce) Ca4(Ce,Y)2(Ti,Al,Fe,[])2[Si4B4O22](OH)2 P 2/a 2/m |
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54.2.2.4 Hellandite-(Ce)! (Ca3REE)4Ce2Al[]2[Si4B4O22](OH)2 P 2/a 2/m |
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54.2.2.5 Mottanaite-(Ce)! Ca4(Ce,Ca)2AlBe2[Si4B4O22]O2 P 2/a 2/m |
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54.2.2.6 Ciprianiite! Ca4[(Th,U)(REE)]2(Al,[])2[Si4B4O22](OH,F)2 P 2/a 2/m |
Strunz Class: |
VIII/F.36-10 VIII - Silicates |
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VIII/F - Inosilicates (chain and band) complex chain structure. Cylindric chains and others |
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VIII/F.36 - Caysichite-(Y) - Tadzhikite-(Ce) series |
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VIII/F.36-02 Grumantite NaHSi2O5·(H2O) F dd2 mm2 |
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VIII/F.36-05 Caysichite-(Y) Y2(Ca,Gd)2Si4O10(CO3)3(H2O,O,OH)·3H20 Ccm21 mm2 |
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VIII/F.36-10 Hellandite-(Y) (Ca,REE)4(Y,Ce)2(Al,[])2[Si4B4O22](OH)2 P 2/a 2/m |
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VIII/F.36-15 Hellandite-(Ce)! (Ca3REE)4Ce2Al[]2[Si4B4O22](OH)2 P 2/a 2/m |
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VIII/F.36-20 Tadzhikite-(Ce) Ca4(Ce,Y)2(Ti,Al,Fe,[])2[Si4B4O22](OH)2 P 2/a 2/m |
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VIII/F.36-25 Tadzhikite-(Y)! Ca4(Y,Ce)2(Ti,Al,Fe,[])2[Si4B4O22](OH)2 P 2/a 2/m |
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VIII/F.36-30 Mottanaite-(Ce)! Ca4(Ce,Ca)2AlBe2[Si4B4O22]O2 P 2/a 2/m |
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VIII/F.36-40 Ciprianiite! Ca4[(Th,U)(REE)]2(Al,[])2[Si4B4O22](OH,F)2 P 2/a 2/m |
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VIII/F.36-60 Ashcroftine-(Y) K5Na5(Y,Ca)12Si28O70(OH)2(CO3)8·8(H2O) I 4/mmm 4/m 2/m 2/m |
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Other Hellandite-(Y) Information
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References: |
NAME( Ford32) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Enc. of Minerals,2nd ed.,1990) |
See Also: |
Links to other databases for Hellandite-(Y) :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -MinDAT
7 -MinMax(Deutsch)
8 -MinMax(English)
9 -Mineralienatlas (Deutsch)
10 -QUT Mineral Atlas
11 - Uranium Minerals
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Print or Cut-and-Paste your Hellandite-(Y) Specimen Label here :
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Hellandite-(Y)
(Ca,REE)4(Y,Ce)2(Al,[ ])2[Si4B4O22](OH)2
Dana No: 54.2.2.1 Strunz No: VIII/F.36-10
Locality:
Notes:
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