General Gismondine Information
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Chemical Formula: |
Ca2Al4Si4O16·9(H2O) |
Composition: |
Molecular Weight = 718.55 gm |
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Calcium 11.16 % Ca 15.61 % CaO |
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Aluminum 15.02 % Al 28.38 % Al2O3 |
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Silicon 15.63 % Si 33.45 % SiO2 |
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Hydrogen 2.52 % H 22.56 % H2O |
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Oxygen 55.67 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
Ca2Al4Si4O16·9(H2O) |
Environment: |
Alteration product of plagioclase. |
IMA Status: |
Valid Species (Pre-IMA) 1817 |
Locality: |
Capo di Bove, near Rome, Italy. Link to MinDat.org Location Data. |
Name Origin: |
Named after the Italian mineralogist, Carlo Giuseppe Gismondi (1762-1824), lecturer in Mineralogy in Rome. |
Synonym: |
Abrazite |
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Aricite |
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Gismondite |
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ICSD 61439 |
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PDF 39-1373 |
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Zeagonite |
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Gismondine Image |
Images:
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Gismondine Crystallography
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Axial Ratios: |
a:b:c =0.9441:1:0.9271 |
Cell Dimensions: |
a = 10.023, b = 10.616, c = 9.843, Z = 2; beta = 92.42° V = 1,046.40 Den(Calc)= 2.28 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 21/c |
X Ray Diffraction: |
By Intensity(I/Io): 2.71(1), 3.19(0.7), 4.25(0.7), |
Crystal Structure:
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Fischer K F , American Mineralogist , 48 (1963) p.664-672, The crystal structure determination of the zeolite gismondite. CaAl2Si2O8.4H2O
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Physical Properties of Gismondine
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Cleavage: |
[101] Imperfect |
Color: |
Blue white, Colorless, Gray, White, Red. |
Density: |
2.26 |
Diaphaniety: |
Transparent to translucent |
Fracture: |
Conchoidal - Fractures developed in brittle materials characterized by smoothly curving surfaces, (e.g. quartz). |
Habit: |
Globular - Spherical, or nearly so, rounded forms (e.g. wavellite). |
Habit: |
Pseudo Tetragonal - Crystals show a tetragonal shape. |
Hardness: |
4-5 - Fluorite-Apatite |
Luster: |
Vitreous (Glassy) |
Streak: |
white |
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Optical Properties of Gismondine
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Gladstone-Dale: |
CI meas= -0.003 (Superior) - where the CI = (1-KPDmeas/KC) CI calc= 0.006 (Superior) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2364,KPDmeas= 0.2385,KC= 0.2378 |
Optical Data: |
Biaxial (-), a=1.536, b=1.539, g=1.542, bire=0.0060, 2V(Calc)=88, 2V(Meas)=84. |
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Calculated Properties of Gismondine
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Electron Density: |
relectron=2.30 gm/cc note: rGismondine =2.26 gm/cc. |
Fermion Index |
Fermion Index = 0.00772 Boson Index = 0.99228 |
Photoelectric: |
PEGismondine = 2.44 barns/electron U=PEGismondine x relectron= 5.61 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Gismondine is Not Radioactive |
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Gismondine Classification
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Dana Class: |
77.1.3.1 (77)Tectosilicate Zeolite group |
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(77.1)true zeolites |
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(77.1.3)Gismondine and related species |
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77.1.3.1 Gismondine Ca2Al4Si4O16·9(H2O) P 21/c 2/m |
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77.1.3.2 Amicite K2Na2Al4Si4O16·5(H2O) I2 2 |
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77.1.3.3 Garronite Na2Ca5Al12Si20O64·27(H2O) I 41/a 4/m |
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77.1.3.4 Gobbinsite (Na2,Ca)2K2Al6Si10O32·12(H2O) P mn21 mm2 |
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77.1.3.5 Harmotome (Ba,Na,K)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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77.1.3.6 Phillipsite-Na (Na,K,Ca)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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77.1.3.6a Phillipsite-Ca! (Ca,K,Na)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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77.1.3.6b Phillipsite-K! (K,Na,Ca)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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77.1.3.8 Perlialite K8Tl4Al12Si24O72·20(H2O) P 6/mmm 6/m 2/m 2/m |
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77.1.3.9 Paulingite-K (K2,Ca,Na2,Ba)5Al10Si35O90·45(H2O) Im3m 4/m 3 2/m |
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77.1.3.9a Paulingite-Na! (Na2,K2,Ca,Ba)5Al10Si35O90·45(H2O) Im3m 4/m 3 2/m |
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77.1.3.9b Paulingite-Ca! (Ca,K,Na,Ba)5[Al10Si35O84]·34(H2O) Im3m 4/m 3 2/m |
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77.1.3.10 Mazzite K2CaMg2(Al,Si)36O72·28(H2O) P 63/mmc 6/m 2/m 2/m |
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77.1.3.11 Merlinoite (K,Ca,Na,Ba)7Si23Al9O64·23(H2O) I mmm 2/m 2/m 2/m |
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77.1.3.12 Montesommaite (K,Na)9Al9Si23O64·10(H2O) F dd2 mm2 |
Strunz Class: |
VIII/J.25-20 VIII - Silicates |
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VIII/J - Tectosilicates (network), with zeolite-structure, Bladed Zeolites |
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VIII/J.25 - Zeolite group, Amicite - Phillipsite - Yugawaralite series |
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VIII/J.25-10 Amicite K2Na2Al4Si4O16·5(H2O) I2 2 |
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VIII/J.25-20 Gismondine Ca2Al4Si4O16·9(H2O) P 21/c 2/m |
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VIII/J.25-30 Gobbinsite (Na2,Ca)2K2Al6Si10O32·12(H2O) P mn21 mm2 |
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VIII/J.25-40 Garronite Na2Ca5Al12Si20O64·27(H2O) I 41/a 4/m |
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VIII/J.25-50 Phillipsite-Na (Na,K,Ca)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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VIII/J.25-55 Phillipsite-K! (K,Na,Ca)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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VIII/J.25-60 Phillipsite-Ca! (Ca,K,Na)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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VIII/J.25-70 Harmotome (Ba,Na,K)1-2(Si,Al)8O16·6(H2O) P 21/m 2/m |
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VIII/J.25-75 Montesommaite (K,Na)9Al9Si23O64·10(H2O) F dd2 mm2 |
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VIII/J.25-80 Merlinoite (K,Ca,Na,Ba)7Si23Al9O64·23(H2O) I mmm 2/m 2/m 2/m |
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VIII/J.25-90 Yugawaralite CaAl2Si6O16·4(H2O) Pc m |
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Other Gismondine Information
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References: |
NAME( Duda&Rejl90) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(Ford32) |
See Also: |
Links to other databases for Gismondine :
1 - Alkali-Nuts(English)
2 - Alkali-Nuts(Francais)
3 -Am. Min. Crystal Structure Database
4 -Athena
5 - Crocoite.com Mineral Locations
6 - EUROmin Project
7 -Google Images
8 -Google Scholar
9 -Handbook of Mineralogy (MinSocAm)
10 -Handbook of Mineralogy (UofA)
11 -MinDAT
12 -MinMax(Deutsch)
13 -MinMax(English)
14 -Mineralienatlas (Deutsch)
15 -QUT Mineral Atlas
16 - WWW-MINCRYST
17 -Zeolite Database by Bruno Herreros
18 -École des Mines de Paris
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Gismondine
Ca2Al4Si4O16·9(H2O)
Dana No: 77.1.3.1 Strunz No: VIII/J.25-20
Locality:
Notes:
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