General Chalcophanite Information
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Chemical Formula: |
(Zn,Fe++,Mn++)Mn++++3O7·3(H2O) |
Composition: |
Molecular Weight = 459.22 gm |
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Manganese 40.68 % Mn 6.18 % MnO / 56.79 % MnO2 |
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Zinc 17.09 % Zn 21.27 % ZnO |
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Iron 6.08 % Fe 7.82 % FeO |
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Hydrogen 1.32 % H 11.77 % H2O |
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Oxygen 34.84 % O |
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______ ______ |
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100.00 % 103.83 % = TOTAL OXIDE |
Empirical Formula: |
Zn1.2Fe2+0.5Mn2+0.4Mn4+3O7·3(H2O) |
Environment: |
Common component of the weathered zone above Zn-Mn base metal deposits. |
IMA Status: |
Valid Species (Pre-IMA) 1875 |
Locality: |
Sterling Hill, near Ogdensburg, Sussex Co., New Jersey, USA. Link to MinDat.org Location Data. |
Name Origin: |
From the Greek for "copper" and "to appear," for the mineral's change in color on ignition. |
Synonym: |
Hydrofranklinite |
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ICSD 202700 |
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PDF 15-807 |
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Chalcophanite Image |
Images:
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Chalcophanite
Comments: Large mass of rounded gray-black chalcophanite.
Location: Sterling Mine, Sterling Hill, Ogdensburg, Franklin Mining District, Sussex Co., New Jersey, USA.
Scale: 14x11x7 cm.
© John Betts - Fine Minerals |
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Chalcophanite Crystallography
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Axial Ratios: |
a:c = 1:2.76038 |
Cell Dimensions: |
a = 7.533, c = 20.794, Z = 5; V = 1,021.89 Den(Calc)= 3.73 |
Crystal System: |
Trigonal - RhombohedralH-M Symbol ( 3) Space Group: R 3 |
X Ray Diffraction: |
By Intensity(I/Io): 6.96(1), 3.5(0.6), 4.08(0.5), |
Forms:
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Crystal Structure:
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Post J E , Appleman D E , American Mineralogist , 73 (1988) p.1401-1404, Chalcophanite, ZnMn3O7.3(H2O): New crystal-structure determinations, Locality: Bisbee, Arizona, Note: U(1,2) of O3 altered to match symmetry constraints, Note: H positions determined by energy modelling
View Additional jPOWD Structure files for Chalcophanite
[1]
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Physical Properties of Chalcophanite
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Cleavage: |
[???] Perfect |
Color: |
Blue, Bluish black, Black. |
Density: |
3.91 |
Diaphaniety: |
Opaque |
Fracture: |
Flexible - Flexible fragments. |
Habit: |
Foliated - Two dimensional platy forms. |
Habit: |
Stalactitic - Shaped like pendant columns as stalactites or stalagmites (e.g. calcite). |
Hardness: |
2.5 - Finger Nail |
Luminescence: |
Non-fluorescent. |
Luster: |
Metallic |
Magnetism: |
Nonmagnetic |
Streak: |
brown |
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Optical Properties of Chalcophanite
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Dichroism (e): |
deep red. |
Dichroism (w): |
opaque black. |
Gladstone-Dale: |
CI meas= -0.414 (Poor) - where the CI = (1-KPDmeas/KC) CI calc= -0.482 (Poor) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.4625,KPDmeas= 0.4412,KC= 0.3121 |
Optical Data: |
Uniaxial (-), e=2.72, w=2.73, bire=0.0100. |
RL Anisotrophism: |
Very strong. |
RL Color: |
White with deep red internal reflections. |
RL Pleochroism: |
Very strong, in gray and white. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Chalcophanite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
11.40 |
38.00 |

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| 420 nm |
11.00 |
36.60 |

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| 440 nm |
10.60 |
35.20 |

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| 460 nm |
10.30 |
33.80 |

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| 480 nm |
10.00 |
32.20 |

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| 500 nm |
9.80 |
30.70 |

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| 520 nm |
9.80 |
29.20 |

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| 540 nm |
9.70 |
28.00 |

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| 560 nm |
9.50 |
26.90 |

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| 580 nm |
9.30 |
26.20 |

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| 600 nm |
9.30 |
25.80 |

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| 620 nm |
9.20 |
25.40 |

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| 640 nm |
9.20 |
24.80 |

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| 660 nm |
9.00 |
24.40 |

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| 680 nm |
8.90 |
24.00 |

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| 700 nm |
8.90 |
23.80 |

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Calculated Relative Intensity Colors of Chalcophanite in Air
Relative Intensity |
0% |
100% |
200% |
300% |
400% |
500% |
600% |
700% |
800% |
900% |
940% |
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Calculated Properties of Chalcophanite
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Electron Density: |
relectron=3.75 gm/cc note: rChalcophanite =3.91 gm/cc. |
Fermion Index |
Fermion Index = 0.00846 Boson Index = 0.99154 |
Photoelectric: |
PEChalcophanite = 20.91 barns/electron U=PEChalcophanite x relectron= 78.33 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Chalcophanite is Not Radioactive |
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Chalcophanite Classification
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Dana Class: |
7.8.2.1 (7)Multiple Oxides |
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(7.8)where A B (O)2·x(H2O) |
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(7.8.2)Dana Group |
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7.8.2.1 Chalcophanite (Zn,Fe,Mn)Mn3O7·3(H2O) R 3 3 |
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7.8.2.2 Aurorite (Mn,Ag,Ca)Mn3O7·3(H2O) P1 1 |
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7.8.2.3 Jianshuiite (Mg,Mn)Mn3O7·3(H2O) R 3 or R 3 Trig |
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7.8.2.4 Ernienickelite NiMn3O7·3(H2O) R 3 or R 3 Trig |
Strunz Class: |
IV/F.11-20 IV - Oxides |
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IV/F - Hydroxides and oxidic hydrates, water-bearing oxides with layered structure |
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IV/F.11 - Jiansuiite - Birnessite series |
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IV/F.11-05 Jianshuiite (Mg,Mn)Mn3O7·3(H2O) R 3 or R 3 Trig |
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IV/F.11-10 Aurorite (Mn,Ag,Ca)Mn3O7·3(H2O) P1 1 |
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IV/F.11-15 Ernienickelite NiMn3O7·3(H2O) R 3 or R 3 Trig |
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IV/F.11-20 Chalcophanite (Zn,Fe,Mn)Mn3O7·3(H2O) R 3 3 |
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IV/F.11-25 Cianciulliite Mn(Mg,Mn)2Zn2(OH)10·2-4(H2O) C 2/m 2/m |
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IV/F.11-30 Birnessite (Na,Ca,K)x(Mn,Mn)2O4·1.5(H2O) C 2/m 2/m |
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Other Chalcophanite Information
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References: |
NAME( AntBidBlaNic3) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Chalcophanite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - Crocoite.com Mineral Locations
4 - EUROmin Project
5 - Franklin Minerals(Dunn)
6 - Franklin Minerals(Palache)
7 -Google Images
8 -Google Scholar
9 -MinDAT
10 -MinMax(Deutsch)
11 -MinMax(English)
12 -Mineralienatlas (Deutsch)
13 -QUT Mineral Atlas
14 - WWW-MINCRYST
15 -École des Mines de Paris
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Print or Cut-and-Paste your Chalcophanite Specimen Label here :
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Chalcophanite
(Zn,Fe++,Mn++)Mn++++3O7·3(H2O)
Dana No: 7.8.2.1 Strunz No: IV/F.11-20
Locality:
Notes:
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