General Alluaudite Information
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Chemical Formula: |
NaCaFe++(Mn,Fe++,Fe+++,Mg)2(PO4)3 |
Composition: |
Molecular Weight = 482.77 gm |
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Sodium 2.86 % Na 3.85 % Na2O |
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Calcium 0.83 % Ca 1.16 % CaO |
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Magnesium 0.50 % Mg 0.83 % MgO |
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Manganese 13.66 % Mn 17.63 % MnO |
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Iron 23.14 % Fe 33.08 % Fe2O3 |
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Phosphorus 19.25 % P 44.10 % P2O5 |
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Oxygen 39.77 % O |
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______ ______ |
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100.00 % 100.66 % = TOTAL OXIDE |
Empirical Formula: |
Na0.6Mn2+0.2Ca0.1Mn2+Fe3+2Mg0.1(PO4)3 |
Environment: |
Sodium metasomatism of triphylite-lithiophilite phosphatic nodules in granite pegmatites. |
IMA Status: |
Valid Species (Pre-IMA) 1848 |
Locality: |
La Vilate quarry, near Chanteloube, Haute-Vienne, France. Link to MinDat.org Location Data. |
Name Origin: |
Named for Francois Alluaud, mining engineer of Limoges, France, who discovered the mineral. |
Synonym: |
Huhnerkobelite |
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ICSD 75441 |
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PDF 42-581 |
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Alluaudite Image |
Images:
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Alluaudite
Comments: Nearly pure crystalline dark green brown mass of alluaudite.
Location: Warusenge Pegmatite, Buranga, Rwanda.
Scale: Size Not Given.
© John Veevaert |
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Images:
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Alluaudite Crystallography
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Axial Ratios: |
a:b:c =0.9577:1:0.5109 |
Cell Dimensions: |
a = 12.004, b = 12.533, c = 6.404, Z = 4; beta = 114.4° V = 877.40 Den(Calc)= 3.65 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: C 2/c |
X Ray Diffraction: |
By Intensity(I/Io): 2.73(1), 6.3(0.8), 3.07(0.65), |
Crystal Structure:
Mouse
drag1 - LMB Manipulate Structure
drag2 - RMB Resize/Rotate
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H - Help Screen
I - Data Info
A - Atoms On/Off
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Help on Above
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Moore P B , American Mineralogist , 56 (1971) p.1955-1975, Crystal chemistry of the alluaudite structure type: Contribution to the, paragenesis of pegmatite phosphate giant crystals
View Additional jPOWD Structure files for Alluaudite
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Physical Properties of Alluaudite
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Cleavage: |
[010] Good, [110] Good |
Color: |
Brownish yellow, Green, Yellow, Black. |
Density: |
3.45 - 3.58, Average = 3.51 |
Diaphaniety: |
Subtranslucent to Opaque |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Nodular - Tuberose forms having irregular protuberances over the surface. |
Habit: |
Platy - Sheet forms (e.g. micas). |
Hardness: |
5-5.5 - Apatite-Knife Blade |
Streak: |
brownish yellow |
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Optical Properties of Alluaudite
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Gladstone-Dale: |
CI meas= 0.007 (Superior) - where the CI = (1-KPDmeas/KC) CI calc= 0.044 (Good) - where the CI = (1-KPDcalc/KC)
KPDcalc= 0.2209,KPDmeas= 0.2294,KC= 0.2311 |
Optical Data: |
Biaxial (+), a=1.782, b=1.802, g=1.835, bire=0.0530, 2V(Calc)=78, 2V(Meas)=50-90. Dispersion r > v moderate. |
Pleochroism (x): |
pale olive green, straw yellow, or greenish yellow. |
Pleochroism (z): |
pale olive greenish or brownish yellow. |
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Calculated Properties of Alluaudite
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Electron Density: |
relectron=3.39 gm/cc note: rAlluaudite =3.52 gm/cc. |
Fermion Index |
Fermion Index = 0.00561 Boson Index = 0.99439 |
Photoelectric: |
PEAlluaudite = 11.57 barns/electron U=PEAlluaudite x relectron= 39.22 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Alluaudite is Not Radioactive |
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Alluaudite Classification
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Dana Class: |
38.2.3.6 (38)Anhydrous Phosphates, etc |
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(38.2)(A+ B++)5 (XO4)3 |
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(38.2.3)Alluaudite-Wyllieite Group (Alluaudite Subgroup) |
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38.2.3.1 Ferrohagendorfite* (Na,Ca)2Fe(Fe,Fe)2(PO4)3 I 21/a 2/m |
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38.2.3.2 Hagendorfite NaCaMn(Fe,Fe,Mg)2(PO4)3 I 21/a 2/m |
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38.2.3.3 Varulite NaCaMn(Mn,Fe,Fe)2(PO4)3 C 2/c 2/m |
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38.2.3.4 Maghagendorfite NaMgMn(Fe,Fe)2(PO4)3 I 21/a 2/m |
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38.2.3.5 Ferroalluaudite NaCaFe(Fe,Mn,Fe,Mg)2(PO4)3 C 2/a 2/m |
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38.2.3.6 Alluaudite NaCaFe(Mn,Fe,Fe,Mg)2(PO4)3 C 2/c 2/m |
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38.2.3.7 Odanielite Na(Zn,Mg)3H2(AsO4)3 C 2/c 2/m |
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38.2.3.8 Johillerite Na(Mg,Zn)3Cu(AsO4)3 I2/c 2/m |
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38.2.3.9 Nickenichite Na0,8Ca0,4(Mg,Fe,Al)3Cu0,4(AsO4)3 C 2/c 2/m |
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38.2.3.10 Yazganite! NaFe2(Mg,Mn)(AsO4)3·H2O C 2/c 2/m |
Strunz Class: |
VII/A.06-70 VII - Phosphates, Arsenates and Vanadates |
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VII/A - Waterfree phosphates [PO4]3- without unfamiliar anions, cations of medium and big size: Mg, Mn,Fe, Cu, Zn, and Ca, Na |
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VII/A.06 - Alluaudite- Hagendorfite group |
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VII/A.06-10 Qingheiite Na2(Mn,Mg,Fe)(Al,Fe)(PO4)3 P 21/n 2/m |
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VII/A.06-20 Bobfergusonite Na2Mn5FeAl(PO4)6 P 21/n 2/m |
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VII/A.06-30 Ferrowyllieite (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 P 21/n 2/m |
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VII/A.06-40 Wyllieite (Na,Ca,Mn)(Mn,Fe)(Fe,Fe,Mg)Al(PO4)3 P 21/n 2/m |
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VII/A.06-50 Rosemaryite (Na,Ca,Mn)(Mn,Fe)(Fe,Fe,Mg)Al(PO4)3 P 21/n 2/m |
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VII/A.06-60 Ferroalluaudite NaCaFe(Fe,Mn,Fe,Mg)2(PO4)3 C 2/a 2/m |
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VII/A.06-70 Alluaudite NaCaFe(Mn,Fe,Fe,Mg)2(PO4)3 C 2/c 2/m |
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VII/A.06-80 Maghagendorfite NaMgMn(Fe,Fe)2(PO4)3 I 21/a 2/m |
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VII/A.06-85 Ferrohagendorfite* (Na,Ca)2Fe(Fe,Fe)2(PO4)3 I 21/a 2/m |
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VII/A.06-90 Hagendorfite NaCaMn(Fe,Fe,Mg)2(PO4)3 I 21/a 2/m |
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VII/A.06-100 Varulite NaCaMn(Mn,Fe,Fe)2(PO4)3 C 2/c 2/m |
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VII/A.06-110 Arseniopleite (Ca,Na)(Na,Pb)Mn(Mn,Mg,Fe)2(AsO4)3 I2/a 2/m |
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VII/A.06-120 Caryinite (Na,Pb)(Ca,Na)(Ca,Mn)(Mn,Mg)2(AsO4)3 I2/c 2/m |
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Other Alluaudite Information
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References: |
NAME( AntBidBlaNic4) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic4) |
See Also: |
Links to other databases for Alluaudite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - Scandinavian mineral gallery
13 - WWW-MINCRYST
14 -École des Mines de Paris
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Print or Cut-and-Paste your Alluaudite Specimen Label here :
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Alluaudite
NaCaFe++(Mn,Fe++,Fe+++,Mg)2(PO4)3
Dana No: 38.2.3.6 Strunz No: VII/A.06-70
Locality:
Notes:
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