General Marokite Information
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Chemical Formula: |
CaMn+++2O4 |
Composition: |
Molecular Weight = 213.95 gm |
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Calcium 18.73 % Ca 26.21 % CaO |
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Manganese 51.36 % Mn 73.79 % Mn2O3 |
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Oxygen 29.91 % O |
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______ ______ |
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100.00 % 100.00 % = TOTAL OXIDE |
Empirical Formula: |
CaMn3+2O4 |
Environment: |
In hydrothermal manganese oxide deposits. |
IMA Status: |
Approved IMA 1963 |
Locality: |
Tachgagalt, Ouarzazate, Morocco. Morocco in French "Maroc". Link to MinDat.org Location Data. |
Name Origin: |
Named for the locality. |
Synonym: |
ICSD 28374 |
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PDF 16-709 |
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Marokite Image |
Images:
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Marokite Crystallography
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Axial Ratios: |
a:b:c =0.968:1:0.315 |
Cell Dimensions: |
a = 9.71, b = 10.03, c = 3.16, Z = 4; V = 307.76 Den(Calc)= 4.62 |
Crystal System: |
Orthorhombic - DipyramidalH-M Symbol (2/m 2/m 2/m) Space Group: Pmab |
X Ray Diffraction: |
By Intensity(I/Io): 2.22(1), 2.71(1), 2.29(0.8), |
Crystal Structure:
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Ross C R , Rubie D C , Paris E , American Mineralogist , 75 (1990) p.1249-1252, Rietveld refinement of the high-pressure polymorph of Mn3O4
View Additional jPOWD Structure files for Marokite
[1]
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Physical Properties of Marokite
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Cleavage: |
[100] Perfect, [001] Good |
Color: |
Black. |
Density: |
4.64 |
Diaphaniety: |
Opaque |
Habit: |
Fibrous - Crystals made up of fibers. |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Hardness: |
6.5 - Pyrite |
Luster: |
Metallic |
Streak: |
red brown |
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Optical Properties of Marokite
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Optical Data: |
Biaxial (-) |
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NCalc= 2.28 - from Gladstone-Dale relationship (KC = 0.2771) where Ncalc=Dcalc*KC+1
NCalc= 2.29 - from Gladstone-Dale relationship (KC = 0.2771) where Ncalc=Dmeas*KC+1 |
Pleochroism (x): |
safflower red. |
RL Anisotrophism: |
Strong, yellowish green to greenish yellow. |
RL Bireflectance: |
Yellowish gray to gray-brown. |
RL Color: |
Light gray to brown, with carmine-red internal reflections. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Marokite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
20.20 |
22.90 |

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| 420 nm |
19.30 |
21.90 |

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| 440 nm |
18.40 |
20.90 |

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| 460 nm |
17.70 |
20.00 |

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| 480 nm |
17.00 |
19.30 |

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| 500 nm |
16.50 |
18.70 |

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| 520 nm |
16.20 |
18.30 |

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| 540 nm |
16.00 |
18.20 |

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| 560 nm |
16.00 |
18.40 |

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| 580 nm |
16.00 |
18.70 |

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| 600 nm |
15.90 |
18.60 |

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| 620 nm |
15.70 |
18.30 |

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| 640 nm |
15.50 |
18.00 |

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| 660 nm |
15.40 |
17.80 |

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| 680 nm |
15.20 |
17.50 |

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| 700 nm |
15.10 |
17.30 |

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Calculated Relative Intensity Colors of Marokite in Air
Relative Intensity |
0% |
60% |
100% |
120% |
180% |
240% |
300% |
360% |
420% |
480% |
540% |
550% |
| R1 |
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| R2 |
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Calculated Properties of Marokite
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Electron Density: |
relectron=4.41 gm/cc note: rMarokite =4.62 gm/cc. |
Fermion Index |
Fermion Index = 0.00039 Boson Index = 0.99961 |
Photoelectric: |
PEMarokite = 15.72 barns/electron U=PEMarokite x relectron= 69.23 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Marokite is Not Radioactive |
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Marokite Classification
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Dana Class: |
7.2.10.1 (7)Multiple Oxides |
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(7.2)(A+ B++)2 X4 Spinel group |
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(7.2.10)Dana Group |
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7.2.10.1 Marokite CaMn2O4 Pmab 2/m 2/m 2/m |
Strunz Class: |
IV/B.05-60 IV - Oxides |
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IV/B - Oxides with metal : oxygen = 3:4 (spinel type M3O4 and related) |
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IV/B.05 - Hausmannite - Filipstadite series |
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IV/B.05-10 Hausmannite MnMn2O4 I 41/amd 4/m 2/m 2/m |
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IV/B.05-20 Iwakiite Mn(Fe,Mn)2O4 P 41/nnm 4/m 2/m 2/m |
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IV/B.05-30 Donathite? (Fe,Mg)(Cr,Fe)2O4 P 4/nnm 4/m 2/m 2/m |
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IV/B.05-40 Hetaerolite ZnMn2O4 I 41/amd 4/m 2/m 2/m |
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IV/B.05-50 Hydrohetaerolite Zn2Mn4O8·(H2O) I 41/amd 4/m 2/m 2/m |
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IV/B.05-60 Marokite CaMn2O4 Pmab 2/m 2/m 2/m |
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IV/B.05-65 Tegengrenite! (Mg,Mn)2Sb0.5(Mn,Si,Ti)0.5O4 R 3 or R 3- Trig |
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IV/B.05-80 Filipstadite (Mn,Mg)4SbFeO8 pseudo ISO 2/m 2/m 2/m |
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Other Marokite Information
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References: |
NAME( AntBidBlaNic3) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic3) |
See Also: |
Links to other databases for Marokite :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 - WWW-MINCRYST
13 -École des Mines de Paris
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Print or Cut-and-Paste your Marokite Specimen Label here :
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Marokite
CaMn+++2O4
Dana No: 7.2.10.1 Strunz No: IV/B.05-60
Locality:
Notes:
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