General Zinkenite Information
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Chemical Formula: |
Pb9Sb22S42 |
Composition: |
Molecular Weight = 5,890.07 gm |
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Antimony 45.47 % Sb |
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Lead 31.66 % Pb |
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Sulfur 22.87 % S |
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______ |
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100.00 % |
Empirical Formula: |
Pb9Sb22S42 |
Environment: |
Constituent mineral in hydrothermal veins associated with base metal deposits. |
IMA Status: |
Valid Species (Pre-IMA) 1826 |
Locality: |
Wolfsberg, Germany. Link to MinDat.org Location Data. |
Name Origin: |
Named after the mineralogist, J. K. L. Zincken (1798-1862). |
Synonym: |
ICSD 61191 |
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PDF 45-1424 |
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Zinckenite |
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Zinkenite Image |
Images:
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Zinkenite
Comments: Jackstraw zinkenite crystals. Individual crystals reach up to 2 cm in length.
Location: Monserrat Mine, Antequera, Oruro, Bolivia.
Scale: 4.5 x 3.2 cm.
© John Veevaert |
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Images:
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Zinkenite Stannite
Comments: Acicular crystals of zinkenite perched on a twinned, crystal of stannite.
Location: Mina San Jos?, Oruro, Bolivia.
Scale: 4 x 2.3 x 1.7 cm.
© Fabre Minerals |
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Zinkenite Crystallography
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Axial Ratios: |
a:c = 1:0.19528 |
Cell Dimensions: |
a = 44.14, c = 8.62, Z = 8; V = 14,544.63 Den(Calc)= 5.38 |
Crystal System: |
Hexagonal - PyramidalH-M Symbol (6) Space Group: P 63 |
X Ray Diffraction: |
By Intensity(I/Io): 3.45(1), 2.8(0.4), 1.828(0.3),1.985(0.3), 2.06(0.2), 2.13(0.2), 3.02(0.2), |
Forms:
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Forms:
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Crystal Structure:
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Portheine J C , Nowacki W , Zeitschrift fur Kristallographie , 141 (1975) p.79-96, Refinement of the crystal structure of zinckenite, Pb6Sb14S27, Sample: Bolivar mine, Cerro Bonete, Bolivia
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Physical Properties of Zinkenite
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Cleavage: |
[1120] Imperfect |
Color: |
Gray, Steel gray. |
Density: |
5.12 - 5.35, Average = 5.23 |
Diaphaniety: |
Opaque |
Fracture: |
Uneven - Flat surfaces (not cleavage) fractured in an uneven pattern. |
Habit: |
Acicular - Occurs as needle-like crystals. |
Habit: |
Prismatic - Crystals Shaped like Slender Prisms (e.g. tourmaline). |
Habit: |
Striated - Parallel lines on crystal surface or cleavage face. |
Hardness: |
3-3.5 - Calcite-Copper Penny |
Luminescence: |
None. |
Luster: |
Metallic |
Magnetism: |
Nonmagnetic |
Streak: |
steel gray |
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Optical Properties of Zinkenite
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RL Anisotrophism: |
Distinct. |
RL Color: |
Gray-white. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Zinkenite in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
39.10 |
44.20 |

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| 420 nm |
39.20 |
44.40 |

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| 440 nm |
39.30 |
44.60 |

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| 460 nm |
39.20 |
44.50 |

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| 480 nm |
39.00 |
44.20 |

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| 500 nm |
38.80 |
43.80 |

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| 520 nm |
38.40 |
43.20 |

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| 540 nm |
37.90 |
42.50 |

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| 560 nm |
37.30 |
41.80 |

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| 580 nm |
36.70 |
41.00 |

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| 600 nm |
36.00 |
40.40 |

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| 620 nm |
35.40 |
39.80 |

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| 640 nm |
34.60 |
39.00 |

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| 660 nm |
34.00 |
38.20 |

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| 680 nm |
33.20 |
37.30 |

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| 700 nm |
32.40 |
36.30 |

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Calculated Relative Intensity Colors of Zinkenite in Air
Relative Intensity |
0% |
30% |
60% |
90% |
100% |
120% |
150% |
180% |
210% |
240% |
250% |
| R1 |
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| R2 |
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Calculated Properties of Zinkenite
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Electron Density: |
relectron=4.63 gm/cc note: rZinkenite =5.38 gm/cc. |
Fermion Index |
Fermion Index = 0.07168 Boson Index = 0.92832 |
Photoelectric: |
PEZinkenite = 722.21 barns/electron U=PEZinkenite x relectron=3,340.56 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Zinkenite is Not Radioactive |
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Zinkenite Classification
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Dana Class: |
3.8.1.1 (3)Sulfides - Sulfosalts |
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(3.8)where 1 < z/y <2 - (A+)i (A++)j [By Cz], A=metals, B=semi-metals, C=non-metals |
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(3.8.1)Dana Group |
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3.8.1.1 Zinkenite Pb9Sb22S42 P 63 6 |
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3.8.1.2 Pillaite! Pb9Sb10S23ClO0.5 C 2/m 2/m |
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3.8.1.3 Pellouxite! (Cu,Ag)Pb10Sb12S27(Cl,S)0.6O C 2/m 2/m |
Strunz Class: |
II/E.26-10 II - Sulfides and sulphosalts |
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II/E - Sulfosalts (S : As,Sb,Bi = x) Lead-Sulfosalts with Arsen and Antimon x = 2.3 - 1.8 |
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II/E.26 - Zinkenite series |
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II/E.26-10 Zinkenite Pb9Sb22S42 P 63 6 |
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II/E.26-20 Scainiite! Pb14Sb30S54O5 C 2/m 2/m |
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Other Zinkenite Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Zinkenite :
1 -Am. Min. Crystal Structure Database
2 - Amethyst Galleries' Mineral Gallery
3 -Athena
4 - EUROmin Project
5 - Franklin Minerals(Dunn)
6 -Google Images
7 -Google Scholar
8 -Handbook of Mineralogy (UofA)
9 - HyperPhysics
10 -MinDAT
11 -MinMax(Deutsch)
12 -MinMax(English)
13 -Mineralienatlas (Deutsch)
14 -QUT Mineral Atlas
15 -École des Mines de Paris
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Print or Cut-and-Paste your Zinkenite Specimen Label here :
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Zinkenite
Pb9Sb22S42
Dana No: 3.8.1.1 Strunz No: II/E.26-10
Locality:
Notes:
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