General Palladoarsenide Information
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Chemical Formula: |
Pd2As |
Composition: |
Molecular Weight = 287.76 gm |
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Arsenic 26.04 % As |
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Palladium 73.96 % Pd |
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______ |
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100.00 % |
Empirical Formula: |
Pd2As |
Environment: |
Minute grains in chalcopyrite that occurs in viens along the footwall of a Cu-Ni deposit. |
IMA Status: |
Approved IMA 1974 |
Locality: |
Oktyabr mine, Talnakh area, Noril'sk district, western Siberia, Russia. Link to MinDat.org Location Data. |
Name Origin: |
Named for the composition. |
Synonym: |
ICSD 26279 |
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PDF 17-227 |
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Search for Palladoarsenide Images |
Images:
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Palladoarsenide Crystallography
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Axial Ratios: |
a:b:c =1.092:1:1.2325 |
Cell Dimensions: |
a = 9.25, b = 8.47, c = 10.44, Z = 18; beta = 94° V = 815.96 Den(Calc)= 10.54 |
Crystal System: |
Monoclinic - PrismaticH-M Symbol (2/m) Space Group: P 2/m |
X Ray Diffraction: |
By Intensity(I/Io): 2.14(1), 2.21(0.9), 2.6(0.7), |
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Physical Properties of Palladoarsenide
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Cleavage: |
[???] Good, [???] Good |
Color: |
Steel gray. |
Density: |
10.42 |
Diaphaniety: |
Opaque |
Fracture: |
Brittle - Generally displayed by glasses and most non-metallic minerals. |
Habit: |
Inclusions - Generally found as inclusions in other minerals. |
Habit: |
Irregular Grains - Occurs as splotchy, anhedral crystals forming inclusions in other minerals or rocks. |
Hardness: |
5 - Apatite |
Luster: |
Metallic |
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Optical Properties of Palladoarsenide
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RL Anisotrophism: |
Moderate, dark gray wiht bluish tint to red-brown in air, dark gray to brownish gray in oil. |
RL Color: |
Grayish white with a slight rose tint. |
Reflectivity |
Standardized Intensity (100%) Reflection Spectra of Palladoarsenide in Air
| λ |
R1 |
R2 |
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∑ R1(λ) |
∑ R2(λ) |
| 400 nm |
44.20 |
45.10 |

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| 420 nm |
46.80 |
46.80 |

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| 440 nm |
48.40 |
48.80 |

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| 460 nm |
49.40 |
50.30 |

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| 480 nm |
50.20 |
51.60 |

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| 500 nm |
51.20 |
53.10 |

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| 520 nm |
51.90 |
54.10 |

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| 540 nm |
52.50 |
54.80 |

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| 560 nm |
53.30 |
55.40 |

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| 580 nm |
53.90 |
55.80 |

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| 600 nm |
54.60 |
56.30 |

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| 620 nm |
55.40 |
57.10 |

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| 640 nm |
56.00 |
57.60 |

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| 660 nm |
56.60 |
58.10 |

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| 680 nm |
57.10 |
58.60 |

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| 700 nm |
57.80 |
59.20 |

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Calculated Relative Intensity Colors of Palladoarsenide in Air
Relative Intensity |
0% |
20% |
40% |
60% |
80% |
100% |
120% |
140% |
160% |
180% |
190% |
| R1 |
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| R2 |
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Calculated Properties of Palladoarsenide
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Electron Density: |
relectron=9.16 gm/cc note: rPalladoarsenide =10.5 gm/cc. |
Fermion Index |
Fermion Index = 0.16516 Boson Index = 0.83484 |
Photoelectric: |
PEPalladoarsenide = 197.46 barns/electron U=PEPalladoarsenide x relectron=1,808.14 barns/cc. |
Radioactivity: |
GRapi = 0 (Gamma Ray American Petroleum Institute Units) Palladoarsenide is Not Radioactive |
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Palladoarsenide Classification
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Dana Class: |
2.4.14.1 (2)Sulfides - Including Selenides and Tellurides |
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(2.4)where Am Bn Xp, with (m+n):p=2:1 |
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(2.4.14)Dana Group |
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2.4.14.1 Palladoarsenide Pd2As P 2/m 2/m |
Strunz Class: |
II/A.05-90 II - Sulfides and sulphosalts |
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II/A - Alloys and alloylike compounds, with metals of the Platinum series, (Palladium) |
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II/A.05 - Atheneite - Genkinite series |
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II/A.05-10 Atheneite (Pd,Hg)3As P 6/mmm 6/m 2/m 2/m |
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II/A.05-20 Vincentite (Pd,Pt)3(As,Sb,Te) Unk Mono |
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II/A.05-30 Stillwaterite Pd8As3 P 3 3 |
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II/A.05-40 Arsenopalladinite Pd8(As,Sb)3 P1 1 |
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II/A.05-50 Isomertieite Pd11Sb2As2 F d3m 4/m 3 2/m |
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II/A.05-60 Mertieite-I Pd11(Sb,As)4 Unk Hex |
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II/A.05-70 Mertieite-II Pd8(Sb,As)3 R 3c 3m |
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II/A.05-80 Stibiopalladinite Pd5Sb2 P 63mc 6mm |
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II/A.05-90 Palladoarsenide Pd2As P 2/m 2/m |
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II/A.05-100 Palladobismutharsenide Pd2(As,Bi) Pmcn,P 21cn Ortho |
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II/A.05-102 Palladodymite! (Pd,Rh)2As P nma 2/m 2/m 2/m |
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II/A.05-105 Rhodarsenide! (Rh,Pd)2As P nma or Pn2 Ortho |
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II/A.05-110 Majakite PdNiAs Unk Hex |
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II/A.05-112 Menshikovite! Pd3Ni2As3 P 63/m,P 63, or P 6322 Hex |
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II/A.05-115 Polkanovite! Rh12As7 P 63m 6/m |
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II/A.05-120 Genkinite (Pt,Pd)4Sb3 P 41212 4 2 2 |
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Other Palladoarsenide Information
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References: |
NAME( AntBidBlaNic1) PHYS. PROP.(Enc. of Minerals,2nd ed.,1990) OPTIC PROP.(AntBidBlaNic1) |
See Also: |
Links to other databases for Palladoarsenide :
1 -Am. Min. Crystal Structure Database
2 -Athena
3 - EUROmin Project
4 -Google Images
5 -Google Scholar
6 -Handbook of Mineralogy (UofA)
7 -MinDAT
8 -MinMax(Deutsch)
9 -MinMax(English)
10 -Mineralienatlas (Deutsch)
11 -QUT Mineral Atlas
12 -École des Mines de Paris
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Print or Cut-and-Paste your Palladoarsenide Specimen Label here :
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Palladoarsenide
Pd2As
Dana No: 2.4.14.1 Strunz No: II/A.05-90
Locality:
Notes:
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